Skip to main content
SpringerLink
Log in

Dinuclear Co(II)-Muconate Complex Displaying Distorted-Trigonal Prismatic Geometry, 2D Supramolecular Array and Weak Antiferromagnetism

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Dinuclear complex [Co2(H2O)4(dmb)2(muc)][muc] (1) (muc = muconate; dmb = 5,5′-dimethyl-2,2′-bipyridine), was obtained by self-assembly solution reaction, under ambient conditions, and it was structurally characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The complex 1 crystallizes in the monoclinic system in the C2/c space group. Noticeably, the six-coordinated Co(II) centers display a distorted-trigonal prismatic configuration. This uncommon coordination geometry is attained due to the hydrogen bonding interactions of the crystalline structure of 1, yielding thus a 2D supramolecular array. Magnetic properties measurements reveal that metaprism 1 exhibits weak antiferromagnetic ordering with θ(C-W) = -14.4 K and an E2 = 0.032 cm−1 accordingly to Curie–Weiss model and Rueff phenomenological approach, respectively.

Graphic Abstract

Influence of the 2D supramolecular array in the distorted trigonal prismatic geometry of a dinuclear Co(II)-muconate complex exhibiting weak antiferromagnetic exchange.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Voloshin YZ, Lebedev AY, Novikov VV, Dolganov AV, Vologzhanina AV, Lebed EG, Pavlov AA, Starikova ZA, Buzin MI, Bubnov YN (2013) Inorg Chim Acta 399:67

    Article  CAS  Google Scholar 

  2. Cremades E, Echeverria J, Alvarez S (2010) Chem Eur J 16:10380–10396

    Article  CAS  Google Scholar 

  3. Santiago A (2015) Chem Rev 115:13447–13483

    Article  Google Scholar 

  4. Sreerama SG, Pal S (2001) Inorg Chem Commun 4:656–660

    Article  Google Scholar 

  5. Friese JC, Krol A, Puke C, Kirschbaum K, Giolando DM (2000) Inorg Chem 39:1496–1500

    Article  CAS  Google Scholar 

  6. Téllez-López A, Jaramillo-García J, Martínez-Domínguez R, Morales-Luckie RA, Camacho-Lopez MA, Escudero R, Sánchez-Mendieta V (2015) Polyhedron 100:373–381

    Article  Google Scholar 

  7. Jaramillo-García J, Sánchez-Mendieta V, García-Orozco I, Morales-Luckie RA, Martínez-Otero D, Téllez-López A, Rosales-Vázquez LD, Escudero R, Morales F (2018) Z Anorg Allg Chem 664:19–22

    Article  Google Scholar 

  8. Grirrane A, Pastor A, Galindo A, Alvarez E, Mealli C, Ienco A, Orlandini A, Rosa P, Caneschi A, Barra A-L, Sanz JF (2011) Chem Eur J 17:10600–10617

    Article  CAS  Google Scholar 

  9. Chen B, Jiang F, Han L, Wu B, Yuan D, Wu M, Hong M (2006) Inorg Chem Commun 9:371–374

    Article  CAS  Google Scholar 

  10. Mir MH, Kitagawa S, Vittal JJ (2008) Inorg Chem 47:7728–7733

    Article  CAS  Google Scholar 

  11. Mir MH, Vittal JJ (2013) Inorg Chim Acta 403:97–101

    Article  CAS  Google Scholar 

  12. Mir MH, Koh LL, Tan GK, Vittal JJ (2010) Angew Chem 122:400–403

    Article  Google Scholar 

  13. Cotton FA, Donahue JP, Murillo CA (2003) J Am Chem Soc 125:5436–5450

    Article  CAS  Google Scholar 

  14. Mukherjee PS, Das N, Kryschenko YK, Arif AM, Stang PJ (2004) J Am Chem Soc 126:2464–2473

    Article  CAS  Google Scholar 

  15. Nagaraja CM, Ugale B (2018) Polyhedron 155:433–440

    Article  CAS  Google Scholar 

  16. Ahmed F, Roy S, Naskar K, Sinha C, Alam SM, Kundu S, Vittal JJ, Mir MH (2016) Cryst Growth Des 16(9):514–5519

    Article  Google Scholar 

  17. Fu D, Yang S, Lu J, Lian H, Qin K (2021). J Clust Sci. https://doi.org/10.1007/s10876-021-01996-8

    Article  Google Scholar 

  18. Bruker, S. A. D. A. B. S., & SAINT, S. (2007). Bruker AXS Inc. Madison, Wisconsin, USA.

  19. Sheldrick GM (2015) SHELXT–Integrated space-group and crystal-structure determination. Acta Crystallogr Sect A 71(1):3–8

    Article  Google Scholar 

  20. Sheldrick GM (2015) Crystal structure refinement with SHELXL. Acta Crystallogr Sect A 71(1):3–8

    Article  Google Scholar 

  21. Hübschle CB, Sheldrick GM, Dittrich B (2011) ShelXle: a Qt graphical user interface for SHELXL. J Appl Crystallogr 44(6):1281–1284

    Article  Google Scholar 

  22. Mihalčiak J, Bertová P, Růžičková Z, Moncol J, Segla P, Boča R (2015) Inorg Chem Commun 56:62–64

    Article  Google Scholar 

  23. Sakiyama H, Ito R, Kumagai H, Inoue K, Sakamoto M, Nishida Y, Yamasaki M (2001) Eur J Inor Chem 8:2027–2032

    Article  Google Scholar 

  24. Padmanabhan M, Joseph JC, Huang X, Li J (2008) Mol J Struct 885:36–44

    Article  CAS  Google Scholar 

  25. Kim JC, Lough AJ, Park H, Kang YC (2006) Inorg Chem Commun 9:514–517

    Article  CAS  Google Scholar 

  26. Van Gorkum R, Buda F, Kooijman H, Spek AL, Bouwman E, Reedijk J (2005) Eur J Inorg Chem 12:2255–2261

    Article  Google Scholar 

  27. Schoedela A, Zaworotko MJ (2014) Chem Sci 5:1269–1282

    Article  Google Scholar 

  28. Murrie M (2010) Chem Soc Rev 39:1986–1995

    Article  CAS  Google Scholar 

  29. Kahn O (1993) Molecular magnetism. VCH Publishers, Hoboken, p 393

    Google Scholar 

  30. Narayanan J, Solano-Peralta A, Ugalde-Saldivar VM, Escudero R, Höpfl H, Sosa-Torres ME (2008) Inorg Chim Acta 361(9–10):2747–2758

    Article  CAS  Google Scholar 

  31. Rabu P, Rueff JM, Huang ZL, Angelov S, Souletie J, Drillon M (2001) Polyhedron 20:1677

    Article  CAS  Google Scholar 

  32. Rueff JM, Masciocchi N, Rabu P, Sironi A, Skoulios A (2001) Eur J Inorg Chem 2011(11):2843

    Article  Google Scholar 

  33. Rueff JM, Masciocchi N, Rabu P, Sironi A, Skoulios A (2002) Chem Eur J 8:1813

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are thankful to M. en C. Alejandra Nuñez Pineda and L. I. A. María Citlalit Martínez Soto (CCIQS UAEM-UNAM) for elemental analysis and computing assistance, respectively. Funding for this work was provided by Universidad Autónoma del Estado de México. JJG thanks CONACyT for PhD scholarship (701384). R. Escudero acknowledges DGAPA-UNAM, project 1T100217. Authors thank M. C. Ana Bobadilla for liquid He, Carlos Reyes Damian for technical support, A. López and A. Pompa-Garcia for help with graphs and figures.

Author information

Authors and Affiliations

  1. Posgrado en Ciencia de Materiales, Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colón y Paseo Tollocan, 50120, Toluca, Estado de México, Mexico

    Jonathan Jaramillo-García

  2. Centro Conjunto de Investigación en Química Sustentable, UAEM-UNAM, Carretera Toluca-Atlacomulco Km. 14.5, San Cayetano, 50200, Toluca, Estado de México, Mexico

    Raúl A. Morales-Luckie, Diego Martínez-Otero & Víctor Sánchez-Mendieta

  3. Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Apartado Postal 70-360, 04510, Mexico, Mexico

    Roberto Escudero & Francisco Morales

Authors
  1. Jonathan Jaramillo-García
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Raúl A. Morales-Luckie
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Diego Martínez-Otero
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Víctor Sánchez-Mendieta
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Roberto Escudero
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Francisco Morales
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Víctor Sánchez-Mendieta.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (TIF 53 KB)

Figure S1. FTIR spectrum of 1.

Supplementary file2 (TIF 4600 KB)

Figure S2. Molecular structure of 1 displaying main hydrogen bonding interactions and Co–Co spatial distances.

Supplementary file3 (PDF 67 KB)

Figure S3. TGA plot of 1.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jaramillo-García, J., Morales-Luckie, R.A., Martínez-Otero, D. et al. Dinuclear Co(II)-Muconate Complex Displaying Distorted-Trigonal Prismatic Geometry, 2D Supramolecular Array and Weak Antiferromagnetism. J Chem Crystallogr 52, 214–222 (2022). https://doi.org/10.1007/s10870-021-00907-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-021-00907-z

Keywords

Search

Navigation