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The X-ray Structures of (R)-2,2′-Dimethyl-1,1′-binaphthyl and (±)-2-Bromomethyl-2′-dibromomethyl-1,1′-binaphthyl

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Abstract

Molecular structures of (R)-2,2′-dimethyl-1,1′-binaphthyl [monoclinic, a = 11.24420 (11), b = 10.56190 (9), c = 13.27180 (13) Å, β = 90.7041 (9)°, space group P21] and (±)-2-bromomethyl-2′-dibromomethyl-1,1′-binaphthyl [triclinic, a = 9.4637 (14), b = 9.9721 (18), c = 9.9922 (19) Å, α = 100.093 (5), β = 97.141 (5), γ = 92.585 (4)°, space group P-1] are reported and compared with those of other simple 2,2′-disubstituted-1,1′-binaphthyls.

Graphic Abstract

Inter-ring bond length and torsion angles are compared with other simple 2,2′-disubstututed-1,1′-binaphthyls.

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Acknowledgements

We would like to thank the Engineering and Physical Sciences Research Council and CRITICAT Centre for Doctoral Training for financial support [Grant Code: EP/L016419/1].

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Authors and Affiliations

  1. EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, KY16 9ST, UK

    R. Alan Aitken, Ryan A. Inwood & Alexandra M. Z. Slawin

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  1. R. Alan Aitken
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  2. Ryan A. Inwood
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  3. Alexandra M. Z. Slawin
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Correspondence to R. Alan Aitken.

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Aitken, R.A., Inwood, R.A. & Slawin, A.M.Z. The X-ray Structures of (R)-2,2′-Dimethyl-1,1′-binaphthyl and (±)-2-Bromomethyl-2′-dibromomethyl-1,1′-binaphthyl. J Chem Crystallogr 51, 497–504 (2021). https://doi.org/10.1007/s10870-020-00876-9

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