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Metal- and Multicarboxylate-Dependent Structural Diversity in Metal–Organic Frameworks with Acylamide-Based Ligand

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Abstract

Three new metal–organic frameworks, [Co2(L)2(ip)2·(H2O)4] (1), [Cu(L)(ip)·(H2O)2] (2), [Cd(µ-H2O)(L)(oip)·(H2O)3.5] (3) (ip = isophthalate, H2oip = 5-hydroxyl-isophthalate), built by acylamide-based ligand and multi-carboxylate ligand were synthesized and structurally characterized by X-ray crystallography. Complex 1 crystallizes in monoclinic space group P21, with a = 9.9171(3), b = 31.9531(10), c = 10.1780(3) Å, β = 118.8270(10)°. Complex 2 crystallizes in the monoclinic space group Cc, with a = 17.7490(3), b = 9.7363(2), c = 18.1202(3) Å, β = 115.0090(10)°. Complex 3 crystallizes in the monoclinic space group P21/c, with a = 9.7670(5), b = 30.3199(15), c = 10.3277(5) Å, β = 102.1680(10)°. All these compounds feature 2D 44 layers with two-fold interpenetration.

Graphical Abstract

Herein we describe the crystal structures of [Co2(L)2(ip)2(H2O)2]·(H2O)2 (1), [Cu(L)(ip)·(H2O)2] (2), [Cd(µ-H2O)(L)(oip)·(H2O)3.5] (3) (ip = isophthalate, H2oip = 5-hydroxyl-isophthalate). All these compounds feature 2D 44 layers with two-fold interpenetration.

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Acknowledgements

We gratefully acknowledge financial support by the National Natural Science Foundation of China (No. 21401112).

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Authors and Affiliations

  1. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, People’s Republic of China

    Huitao Fan, Zhiguo Zhong, Shanshan Liu, Bo Li & Wenxin Duan

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  1. Huitao Fan
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  2. Zhiguo Zhong
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  3. Shanshan Liu
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  4. Bo Li
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  5. Wenxin Duan
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Correspondence to Bo Li.

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Fan, H., Zhong, Z., Liu, S. et al. Metal- and Multicarboxylate-Dependent Structural Diversity in Metal–Organic Frameworks with Acylamide-Based Ligand. J Chem Crystallogr 48, 125–130 (2018). https://doi.org/10.1007/s10870-018-0719-1

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