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Syntheses, Crystal Structures, and Fluorescent Properties of Two Mixed-Ligand Cadmium Coordination Polymers Based on Dicarboxylate and Bis-benzimidazole Ligands

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Abstract

Two cadmium(II) coordination polymers, {[Cd2(HO-bdc)(Hbbop)2]}n (1), and {[Cd2(H2N-bdc)(Hbbop)2]·2(H2O)}n (2), (HO-H2bdc = 5-hydroxyisophthalic acid, H2N-H2bdc = 5-aminoisophthalic acid, and H2bbop = 1,3-bis(benzimidazol-2-yl)-2-oxapropane) have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectra, single crystal X-ray diffraction, and thermogravimetric analyses. Their structures are 2D networks with (63) topology, which are further connected by hydrogen bonds to form 3D supramolecular architectures. Additionally, fluorescent properties of the two complexes are reported.

Graphical Abstract

Two 2D mixed-ligand cadmium coordination polymers with (63) topology were synthesized and characterized.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20971076).

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Authors and Affiliations

  1. State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Yong-Hong Wen, Chang-Geng Chen, Hui-Ling Wen, Xiao-Wei Mu & Kuo Yao

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  1. Yong-Hong Wen
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  2. Chang-Geng Chen
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  3. Hui-Ling Wen
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Correspondence to Yong-Hong Wen.

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Wen, YH., Chen, CG., Wen, HL. et al. Syntheses, Crystal Structures, and Fluorescent Properties of Two Mixed-Ligand Cadmium Coordination Polymers Based on Dicarboxylate and Bis-benzimidazole Ligands. J Chem Crystallogr 48, 12–18 (2018). https://doi.org/10.1007/s10870-018-0711-9

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  • DOI: https://doi.org/10.1007/s10870-018-0711-9

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