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Two Novel Coordination Polymers Based on Semi-rigid Tetrapyridine Fine-Tuned by Different Carboxylates

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Abstract

By utilizing the flexible quadritopic ligand, tetrakis(3-pyridyloxymethyl)methane (L), two novel coordination polymers have been synthesized and structurally characterized. {[Cu3(L)2(acetate)6]·10(H2O)}n has a 1D chain crystal structure with a SP 2-periodic net with the Schläfli symbol {36·46·53} modeled by acetate ions. In {[Cu2(L)(benzoate)4]·2(CH3OH)·H2O}n, we substituted the acetate with benzoate and obtained 2D crystal structure with an novel 2, 3, 4 net with the Schläfli symbol {4·82}2{42·82·102}{8}. The structural results show that utilizing a flexible ligand is a good approach to achieve diversity in coordination polymer structures and could be easily affected by the carboxylate anions.

Graphical Abstract

Two novel coordination polymers assembled from the tetrakis(3-pyridyloxymethylene) methane(L) with copper(II) ions and different carboxylate. Crystal structures and topological analyses of these compounds are presented.

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Acknowledgements

We gratefully acknowledge the National Natural Science Foundation of China (No. 51403079) for generous financial support.

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Authors and Affiliations

  1. Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, School of Chemistry and Environmental Engineering, Jianghan University, Wuhan, 430056, Hubei, People’s Republic of China

    Xin Xiong, Ke-xin Huang, Meng Zhang, Yu-dan Hao & Fan Yu

  2. Key Laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, Hubei, People’s Republic of China

    Bao Li

Authors
  1. Xin Xiong
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  2. Ke-xin Huang
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  3. Meng Zhang
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  4. Yu-dan Hao
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  5. Fan Yu
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  6. Bao Li
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Corresponding authors

Correspondence to Fan Yu or Bao Li.

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Xiong, X., Huang, Kx., Zhang, M. et al. Two Novel Coordination Polymers Based on Semi-rigid Tetrapyridine Fine-Tuned by Different Carboxylates. J Chem Crystallogr 48, 73–77 (2018). https://doi.org/10.1007/s10870-018-0707-5

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  • DOI: https://doi.org/10.1007/s10870-018-0707-5

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