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Six New Complexes Based on Substituted Pyridazine Ligands: Structures and Luminescent Properties

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Abstract

Three structurally related ligands 3-chloro-6-(benzoimidazol-1-yl)pyridazine (L 1), 3-chloro-6-(1,2,4-triazol-1-yl)pyridazine (L 2) and 3,6-bis(imidazol-1-yl)pyridazine (L 3) were designed and synthesized, and six new Zn(II), Co(II), Cu(II) and Cd(II) complexes, namely, [M(L 1)2Cl2] [M = Zn (1) and Co (2)], [Cu(L 2)2(NO3)2(H2O)] (3), [Cu(L 2)2Cl2]∞ (4), [CuL 3(CH3COO)2]∞ (5) and [CdL 3(SCN)2]∞ (6) were synthesized and characterized by elemental analyses, IR spectra as well as single-crystal X-ray diffraction analysis. The analysis reveals that complexes 1, 2 and 3 have a mononuclear structure, 1 and 2 have a similar structure. Complex 3 features a 1D structure with intermolecular O–H⋯O hydrogen bonding interactions. Complex 4 shows a 1D chain structure with bridging Clˉ ions. Complex 5 exhibits a 1D ladder structure. The 2D framework of 6 features are rectangular grid with a (4, 4) topology. Additionally, photoluminescence properties of ligands L 1, L 3 and complexes 1, 2 and 6 have been studied and discussed.

Graphical Abstract

Six new metal-organic complexes were synthesized and structurally characterized, complexes 1, 2 and 3 have a mononuclear structure, complexes 4 and 5 show 1D chain structure, the 2D framework of 6 has a rectangle grid with a (4, 4) topology, moreover, photoluminescence properties of ligands L 1, L 3 and complexes 1, 2 and 6 have been studied and discussed.

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Acknowledgements

This work was financially supported by the Natural Science Funds of XinJiang, China (No. 2015 211C266).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046, People’s Republic of China

    Sheng-Bin Zhou, Ceng-Ceng Du, Xin-fang Wang, Ying-Zhi Han, Jun-Liang Dong & Duo-Zhi Wang

  2. Key Laboratory of Energy Materials Chemistry, Ministry of Education, Institute of Applied Chemistry, Xinjiang University, Urumqi, 830046, Xinjiang, People’s Republic of China

    Duo-Zhi Wang

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  1. Sheng-Bin Zhou
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  2. Ceng-Ceng Du
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  3. Xin-fang Wang
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  4. Ying-Zhi Han
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Correspondence to Duo-Zhi Wang.

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Zhou, SB., Du, CC., Wang, Xf. et al. Six New Complexes Based on Substituted Pyridazine Ligands: Structures and Luminescent Properties. J Chem Crystallogr 47, 215–225 (2017). https://doi.org/10.1007/s10870-017-0699-6

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  • DOI: https://doi.org/10.1007/s10870-017-0699-6

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