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Synthesis, Characterization and X-ray Crystal Structures of the New Mixed Compound Rb1.89Na0.11(SO4)0.89(SeO4)0.11Te(OH)6

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Abstract

At room temperature, the new compound Rb1.89Na0.11(SO4)0.89(SeO4).011Te(OH)6 crystallizes in the monoclinic system with space group P21/c. The unit cell parameters are: a = 13.655 Å (4), b = 6.681 Å (4), c = 11.497 Å, β = 107.07° (3), V = 1002.60(5) Å3, Z = 4 and ρcal = 3.26 g.cm−1. The structure is stabilized by interplanar O–H···O hydrogen bonds involving all the H atoms that belong to the OH groups of the Te(OH)6 octahedra. Raman spectra of the material recorded at various temperatures (300–500 K) in the frequency range 100–1000 cm−1 and IR spectra achieved at room temperature between 600 and 3500 cm−1, confirm the presence of all the phase transitions detected in the material and show that anionic groups coexist independently in the same crystal.

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Acknowledgments

This work is supported by the Ministry of Superior Education and Research.

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Authors and Affiliations

  1. Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Université de Sfax, BP 1171, 3000, Sfax, Tunisia

    M. Abdelhedi, M. Dammak & A. W. Kolsi

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  1. M. Abdelhedi
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  2. M. Dammak
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  3. A. W. Kolsi
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Correspondence to M. Abdelhedi.

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Abdelhedi, M., Dammak, M. & Kolsi, A.W. Synthesis, Characterization and X-ray Crystal Structures of the New Mixed Compound Rb1.89Na0.11(SO4)0.89(SeO4)0.11Te(OH)6 . J Chem Crystallogr 45, 257–265 (2015). https://doi.org/10.1007/s10870-015-0593-z

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