Advertisement

Journal of Chemical Crystallography

, Volume 45, Issue 4, pp 189–192 | Cite as

Synthesis and Structure of a Trigonal Planar Complex with Pyrazole Ligands, [Cu(3,5-Ph2PzH)3][Cl]

  • Tulio Chavez-Gil
  • Joel Lugo
  • David L. Cedeño
  • Christopher G. Hamaker
Original Paper

Abstract

The crystal structure of a trigonal planar copper(I) complex, [Cu-(3,5-Ph2PzH)3][Cl], is reported. In the title compound, one nitrogen atom from each pyrazole ligand is coordinated to the copper(I) ion and each N–H of the pyrazoles forms a hydrogen-bond with the chloride resulting in a trigonal planar geometry about the copper(I) ion. The complex crystallizes in the trigonal space group R \(\overline 3\) with a = b = 13.031(1) Å, c = 37.3187(9) Å, α = β = 90o, γ = 120o , V = 5464.5(2) Å3, Z = 6.

Graphical Abstract

A trigonal planar copper(I) complex with three pyrazole ligands is reported in which the hydrogens of the bound pyrazole ligands are hydrogen bonded with the chloride counter ion.

Keywords

Pyrazole Crystal structure Copper Hydrolysis Hydrogen bonding 

Notes

Acknowledgments

We thank the National Science Foundation (Grant No. CHE-103689) for funding the X-ray diffractometer at Illinois State University. Two of the authors (J. Lugo and T. Ch-G) are grateful to the Ronald E. McNair program (IAUPR-SG; CFDA No. 84.217A grant) for an undergraduate scholarship and financial support.

References

  1. 1.
    Allen FH (2002) Acta Cryst B58:380CrossRefGoogle Scholar
  2. 2.
    Lebel H, Marcoux J-F, Molinaro C, Charette AB (2003) Chem Rev 103:977CrossRefGoogle Scholar
  3. 3.
    Müller P, Fruit C (2003) Chem Rev 103:2905CrossRefGoogle Scholar
  4. 4.
    Liu X, Kilner CA, Halcrow MA (2002) Chem Commun 704Google Scholar
  5. 5.
    Renard SL, Kilner CA, Fisher J, Halcrow MA (2002) J Chem Soc, Dalton Trans 4206Google Scholar
  6. 6.
    Trofimenko S (1993) Chem Rev 93:943CrossRefGoogle Scholar
  7. 7.
    Munoz-Molina JM, Sameeraa WMC, Alvarez E, Maseras F, Belderrain TR, Perez PJ (2001) Inorg Chem 50:2458CrossRefGoogle Scholar
  8. 8.
    Hsu SCN, Chang Y-L, Chuang W-J, Chen H-Y, Lin I-J, Chiang MY, Kao C-L, Chen H-Y (2002) Inorg Chem 51:9297CrossRefGoogle Scholar
  9. 9.
    Fujisawa K, Ono T, Ishikawa Y, Amir N, Miyashita Y, Okamoto K, Lehnert N (2006) Inorg Chem 45:1698CrossRefGoogle Scholar
  10. 10.
    Paulat F, Lehnert N, Ishikawa Y, Okamoto K-I, Fujisawa K (2008) Inorg Chim Acta 361:901CrossRefGoogle Scholar
  11. 11.
    Fujisawa K, Yoshida M, Miyashita Y, Okamoto K (2009) Polyhedron 28:1447CrossRefGoogle Scholar
  12. 12.
    King WA, Yap GPA, Incarvito CD, Rheingold AL, Theopold KH (2009) Inorg Chim Acta 362:4493CrossRefGoogle Scholar
  13. 13.
    Kimani MM, Brumaghim JL, Van Derveer D (2010) Inorg Chem 49:9200CrossRefGoogle Scholar
  14. 14.
    Ardizzola GA, Cenini S, LaMonica G, Masclocchi N, Moret M (1994) Inorg Chem 33:1458CrossRefGoogle Scholar
  15. 15.
    Sorrell TN, Borovik AS, Caswell DS, Grygon C, Spiro TG (1986) J Am Chem Soc 108:5636CrossRefGoogle Scholar
  16. 16.
    Okkersen H, Groeneveld WL, Reedijk J (1973) Recl Trav Chim 92:945CrossRefGoogle Scholar
  17. 17.
    Chavez-Gil T, Cedeño DL, Hamaker CG, Vega M, Rodriguez J (2008) J Mol Struct 888:168CrossRefGoogle Scholar
  18. 18.
    Kitajima N, Fujisawa K, Fujimoto C, Moro-oka Y, Hashimoto S, Kitagawa T, Toriumi K, Tatsumi K (1992) K. Nakamura. J Am Chem Soc 114:1277CrossRefGoogle Scholar
  19. 19.
    Bruker (2013) APEX2 v2013.2-0, Bruker AXS Inc., MadisonGoogle Scholar
  20. 20.
    Farrugia LJ (2012) J Appl Cryst 45:849CrossRefGoogle Scholar
  21. 21.
    Altomare A, Cascarano G, Giacovazzo C, Guagliardi A (1993) J Appl Crystallogr 26:343CrossRefGoogle Scholar
  22. 22.
    Sheldrick GM (1997) SHELX 97, Program for X-ray crystal structure refinement. University of Göttingen, GöttingenGoogle Scholar
  23. 23.
    Goettler PE, Hamaker CG. unpublished resultsGoogle Scholar
  24. 24.
    Bondi A (1964) J Phys Chem 68:441CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.Department of Natural SciencesCoppin State UniversityBaltimoreUSA
  2. 2.Department of Biology, Chemistry and Environmental ScienceInteramerican University of Puerto RicoSan GermanUSA
  3. 3.Department of ChemistryIllinois State UniversityNormalUSA

Personalised recommendations