Abstract
Three new Cd(II) coordination polymers constructed from two structurally related ligands, 1,1′-(1,3-propane)bis-(2-methylbenzimidazole) (pbmb) and 1,1′-(1,4-butanediyl)bis(2-methyl-benzimidazole) (bbmi), have been hydrothermally synthesized: [Cd(pbmb)(hmph)] n (1), [Cd(pbmb)(chdc)] n (2) and [Cd(bbmi)0.5(chdc)] n (3), where H2hmph = homophthalic acid and H2chdc = 1,4-cyclohexanedicarboxylic acid. These complexes were structurally characterized by elemental analysis, IR, and single crystal X-ray diffraction analyses. Complex 1 possesses a two-dimensional 63 honeycombed network structure, which are further extended into a 3D supermolecule framework through weak C–H···O hydrogen bonding interactions. 2 displays an infinite 1D loop-like chain structure, which is further assembled into a 2D supramolecular layer via C–H···O hydrogen bonding interactions. In complex 3, CdII ions are connected by chdc2− anions to form a 1D chain containing binuclear clusters, which is further connected by the bbmi exhibiting a 2D (3,4)-connected network with a point symbol of {42·63·8}{42·6}. The thermal and photoluminescence properties of the three complexes were investigated in detail.
Graphical Abstract
Three Cd(II) coordination polymers constructed by flexible bis-(2-methylbenzimidazole) and dicarboxylate anions co-ligands. These compounds display diverse architectures from 1D to 2D. The various structures indicate that flexible dicarboxylate anions have a remarkable effect on the final structures and topologies.
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Li M, Li D, O’Keeffe M, Yaghi OM (2014) Chem Rev 114:1343
Yoshida J, Nishikiori SI, Kuroda R, Yuge H (2013) Chem Eur J 19:3451
Kanoo P, Matsuda R, Kitaura R, Kitagawa S, Maji TK (2012) Inorg Chem 51:9141
Liu D, Ren ZG, Li HX, Lang JP, Li NY, Abrahams BF (2010) Angew Chem Int Ed 49:4767
Cao LH, Xu QQ, Zang SQ, Hou HW, Mak TC (2013) Cryst Growth Des 13:1812
Chen Y, Wang ZO, Yang Z, Ren ZG, Li HX, Lang JP (2010) Dalton Trans 39:9476
Ji C, Li B, Ma ML, Zang SQ, Hou HW, Mak TC (2012) Cryst Eng Comm 14:3951
Ma DY, Guo HF, Qin L, Li Y, Ruan QT, Huang YW, Xu J (2014) J Chem Crystallogr 44:63
Wang XX, Yu B, Van Hecke K, Cui GH (2014) RSC Adv 4:61281
Li DX, Ni CY, Chen MM, Dai M, Zhang WH, Yan WY, Lang JP (2014) Cryst Eng Comm 16:2158
Chen Q, Chang Z, Song WC, Song H, Hu TL, Bu XH (2013) Angew Chem Int Ed 52:11550
Geng JC, Wang CJ, Wang F, Luo HR, Yang CC, Cui GH (2012) Chin J Inorg Chem 28:1060
Aakeröy CB, Champness NR, Janiak C (2010) Cryst Eng Comm 12:22
Li YW, Ma H, Chen YQ, He KH, Li ZX, Bu XH (2012) Cryst Growth Des 12:189
Chen SS, Chen M, Takamizawa S, Chen MS, Su Z, Sun WY (2011) Chem Commun 47:752
Ma JF, Liu JF, Liu YC, Xing Y, Jia HQ, Lin YH (2000) New J Chem 24:759
Li SL, Lan YQ, Ma JC, Ma JF, Su ZM (2010) Cryst Growth Des 10:1161
Hou HW, Meng XR, Song YL, Fan YT, Zhu Y, Lu HJ, Du CX, Shao WH (2002) Inorg Chem 41:4068
Shi XJ, Wang X, Li LK, Hou HW, Fan YT (2010) Cryst Growth Des 10:2490
Li LL, Yuan RX, Liu LL, Ren ZG, Zheng AX, Cheng HJ, Li HX, Lang JP (2010) Cryst Growth Des 10:1929
Jing W, Ren ZG, Dai M, Chen Y, Lang JP (2011) Cryst Eng Commun 13:5111
Li ZX, Xu Y, Zuo Y, Li L, Pan QH, Hu TL, Bu XH (2009) Cryst Growth Des 9:3904
Li ZX, Hu TL, Ma H, Zeng YF, Li CJ, Tong ML, Bu XH (2010) Cryst Growth Des 10:1138
Liu D, Lang JP, Abrahams BF (2011) J Am Chem Soc 133:11042
Geng JC, Jiao CH, Hao JM, Cui GH (2012) Z Naturforsch 67b: 791
Qin L, Li YH, Ma PJ, Cui GH (2013) J Mol Struct 1051:215
Hao JM, Li YH, Li HH, Cui GH (2014) Transit Metal Chem 39:1
Liu L, Li XL, Xu CY, Han G, Zhao Y, Hou HW, Fan YT (2012) Inorg Chim Acta 391:66
Xu CY, Guo QQ, Wang XJ, Hou HW, Fan YT (2011) Cryst Growth Des 11:1869
Jiang H, Ma JF, Zhang WL, Liu YY, Yang J, Ping GJ, Su ZM (2008) Eur J Inorg Chem 5:745
Sheldrick GM, SADABS (version 2 03) (1996) Program for empirical absorption correction of area detector data. University of Göttingen, Göttingen
Sheldrick GM (2008) Acta Crystallog Sect A64:112
Blatov VA (2012) Struct Chem 23:955
Nakamoto K (1986) Infrared spectra and Raman spectra of inorganic and coordination compounds. Wiley, New York
Thirumurugan A, Natarajan S (2004) Dalton Trans 97:2923
McGarrah JE, Kim YJ, Hissler M, Eisenberg R (2001) Inorg Chem 40:4510
Dai M, Yan WY, Ren ZG, Wang HF, Gong WJ, Li FL, Lang JP (2012) Cryst Eng Commun 14:6230
Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud KP (2008) J Am Chem Soc 130:13850
Zhang LP, Ma JF, Yang J, Liu YY, Wei GH (2009) Cryst Growth Des 9:4660
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Wang, Xx., Hao, Jm., Li, Gy. et al. Syntheses, Structures and Photoluminescence of Three Cd(II) Coordination Polymers Based on Flexible Bis(Benzimidazole) and Dicarboxylate Ligands. J Chem Crystallogr 45, 77–85 (2015). https://doi.org/10.1007/s10870-015-0568-0
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DOI: https://doi.org/10.1007/s10870-015-0568-0