Skip to main content
SpringerLink
Log in

Solvothermal Syntheses and Crystal Structures of Gadolinium Selenidoantimonates [Gd(trien)2]SbSe4 and [Gd(trien)(dien)(SbSe4)]

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Two gadolinium selenidoantimonates [Gd(trien)2]SbSe4 (1) and [Gd(dien)(trien)(SbSe4)] (2) (trien = triethylenetetramine, dien = diethylenetriamine), were prepared by solvothermal reactions of Gd2O3, Sb and Se in trien and mixed trien + dien solvents respectively. Compounds 1 and 2 crystallize in monoclinic space group P21/c and P21/n, respectively. Cell Parameters of 1 are a = 9.2638(17), b = 13.462(3), c = 19.647(4) Å, β = 92.776(3)°, V = 2,447.4(8) Å3, Z = 4. Cell Parameters of 2 are a = 10.210(2), b = 17.602(4), c = 12.377(3) Å, β = 90.280(5)°, V = 2,224.5(9) Å3, Z = 4. In 1 the anion [SbSe4]3− exists as an isolated, charge-compensating anion for the [Gd(trien)2]3+ complex cation. It coordinates to the Gd(III) center of [Gd(dien)(trien)]3+ as a monodentate ligand to form a neutral mixed-coordinate complex [Gd(dien)(trien)(SbSe4)] (2). The coordination to Gd(III) center is influenced by the co-ligands of polyamines.

Graphical Abstract

New lanthanide selenidoantimonates [Gd(trien)2]SbSe4 and [Gd(trien)(dien)(SbSe4)] with 3-dimensional H-bonding network structures were respectively synthesized in trien and mixed trien/dien (trien = triethylenetetramine; dien = diethylenetriamine) solvents under mild solvothermal conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Stephan HO, Kanatzidis MG (1996) J Am Chem Soc 118:12226

    Article  CAS  Google Scholar 

  2. Li J, Chen Z, Wang RJ, Proserpio DM (1999) Coord Chem Rev 190–192:707

    Article  Google Scholar 

  3. Sheldrick WS, Wachhold M (1998) Coord Chem Rev 176:211

    Article  CAS  Google Scholar 

  4. Sheldrick WS (2000) J Chem Soc Dalton Trans 18:3041

    Article  Google Scholar 

  5. Seidlhofer B, Pienack N, Bensch W (2010) Z. Naturforsch 65b:937

  6. Stephan HO, Kanatzidis MG (1997) Inorg Chem 36:6050

    Article  CAS  Google Scholar 

  7. Vaqueiro P, Chippindale AM, Powell AV (2004) Inorg Chem 43:7963

    Article  CAS  Google Scholar 

  8. Rachel JEL, Anthony VP, Ann MC (2005) Polyhedron 24:1941

    Article  Google Scholar 

  9. Stähler R, Mosel B-D, Eckert H, Bensch W (2002) Angew Chem Int Ed 41:4487

    Article  Google Scholar 

  10. Stähler R, Näther C, Bensch W (2003) J Solid State Chem 174:264

    Article  Google Scholar 

  11. Chen Z, Wang RJ, Huang XY, Li J (2000) Acta Crystallogr C 56:1100

    Article  Google Scholar 

  12. Jia DX, Zhang Y, Zhao QX, Deng J (2006) Inorg Chem 45:9812

    Article  CAS  Google Scholar 

  13. Jin QY, Zhu AM, Pan YL, Jia DX (2009) Z Anorg Allg Chem 635:139

    Article  CAS  Google Scholar 

  14. Schur M, Rijnberk H, Näther C, Bensch W (1998) Polyhedron 18:101

    Article  Google Scholar 

  15. Schur M, Bensch W (2002) Z Naturforsch B 57:1

    CAS  Google Scholar 

  16. Engelke L, Stähler R, Schur M, Näther C, Bensch W, Pöttgen R, Möller MH (2004) Z Naturforsch B 59:869

    CAS  Google Scholar 

  17. Bensch W, Näther C, Schur M (1997) Chem Commun 18:1773

    Article  Google Scholar 

  18. van Almsick T, Sheldrick WS (2006) Z Anorg Allg Chem 632:1413

    Article  Google Scholar 

  19. Jia DX, Zhu QY, Dai J, Lu W, Guo WJ (2005) Inorg Chem 44:819

    Article  CAS  Google Scholar 

  20. Jia DX, Zhao QX, Zhang Y, Dai J, Zuo JL (2005) Inorg Chem 44:8861

    Article  CAS  Google Scholar 

  21. Jia DX, Jin QY, Chen JF, Pan YL, Zhang Y (2009) Inorg Chem 48:8286

    Article  CAS  Google Scholar 

  22. Jia DX, Zhao QX, Zhang Y, Dai J, Zhou J (2006) Eur J Inorg Chem 14:2760

    Article  Google Scholar 

  23. Jia DX, Zhu AM, Jin QY, Zhang Y, Jiang WQ (2008) J Solid State Chem 181:2370

    Article  CAS  Google Scholar 

  24. Zhao J, Liang JJ, Pan YL, Zhang Y, Jia DX (2011) J Solid State Chem 184:1451

    Article  CAS  Google Scholar 

  25. Sheldrick GM (2008) Acta Cryst A64:112

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation China (NSFC, No. 21171123).

Author information

Authors and Affiliations

  1. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, No. 199, Renai Road, Suzhou, 215123, People’s Republic of China

    Fang Wang, Chun-ying Tang, Jia-lin Lu, Ya-li Shen, Yong Zhang & Ding-xian Jia

Authors
  1. Fang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chun-ying Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jia-lin Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ya-li Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yong Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ding-xian Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ding-xian Jia.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, F., Tang, Cy., Lu, Jl. et al. Solvothermal Syntheses and Crystal Structures of Gadolinium Selenidoantimonates [Gd(trien)2]SbSe4 and [Gd(trien)(dien)(SbSe4)]. J Chem Crystallogr 45, 61–66 (2015). https://doi.org/10.1007/s10870-015-0564-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-015-0564-4

Keywords

Search

Navigation