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Crystal Structure of 2,2-dimethyl-5-[(2-metylhydrazinyl)methylidene-1,3-dioxan-4,6-dione

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Abstract

The 2,2-dimethyl-5-[(2-metylhydrazinyl)methylidene-1,3-dioxan-4,6-dione has been prepared and its crystal structure of 2,2-dimethyl-5-[(2-metylhydrazinyl)methylidene-1,3-dioxan-4,6-dione (C8H12O4, Mr = 200.19) has been determinated by single-crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic system with space group C2/c and unit cell parameters: a = 27.9436(6), b = 10.1683(3), c = 14.1604(3) Å, β = 100.334(2)° and Z = 16. The final reliability index is 0.0412 for the 2866 observed reflections. The two molecules of 1 are localized in independent part of unit cell. The title compounds are linked through N–H⋯O, C–H⋯O and C–H⋯N hydrogen bonds into 1-D rail-like supramolecular chains.

Graphical Abstract

The 2,2-dimethyl-5-[(2-metylhydrazinyl)methylidene-1,3-dioxan-4,6-dione has been prepared and its crystal structure of 2,2-dimethyl-5-[(2-metylhydrazinyl)methylidene-1,3-dioxan-4,6- has been determinated by single-crystal X-ray diffraction analysis.

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Acknowledgments

This work was supported by the Grants APVV-0038-11; and VEGA 1/0228/12, 1/2594/12 and 1/0829/14.

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Authors and Affiliations

  1. Faculty of Chemical and Food Technology, Institute of Inorganic Chemistry, Technology and Materials, Slovak University of Technology, Radlinskeho 9, 812 37, Bratislava, Slovakia

    Jan Moncol

  2. Faculty of Material Science, Slovak University of Technology, Paulinska 16, 917 24, Trnava, Slovakia

    Jan Lokaj

  3. Faculty of Chemical and Food Technology, Institute of Organic Chemistry, Catalysis and Petrochemistry, Slovak University of Technology, Radlinskeho 9, 812 37, Bratislava, Slovakia

    Denisa Tarabová & Viktor Milata

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  1. Jan Moncol
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  2. Denisa Tarabová
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Correspondence to Jan Moncol.

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Moncol, J., Tarabová, D., Lokaj, J. et al. Crystal Structure of 2,2-dimethyl-5-[(2-metylhydrazinyl)methylidene-1,3-dioxan-4,6-dione. J Chem Crystallogr 44, 466–470 (2014). https://doi.org/10.1007/s10870-014-0538-y

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  • DOI: https://doi.org/10.1007/s10870-014-0538-y

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