Skip to main content
SpringerLink
Log in

Coordination of Bidentate Aroylhydrazone-Based N,N-Donor Ligands to the fac-[Re(CO)3]+ Core

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The reaction of the potentially bidentate aroylhydrazone-based N,N-donor ligands N-(di(pyridin-2-yl)-methylene)benzohydrazide (Hdpmb) and 3-((pyridin-2-yl)methyleneamino)-2,3-dihydro-2-(pyridin-2-yl)quinazolin-4-(1H)one (Hppq) with [Re(CO)5Cl] in alcohol led to the isolation of the neutral complexes fac-[Re(CO)3Cl(Hdpmb)] (1) and fac-[Re(CO)3Cl(Hppq)] (2) respectively. Spectroscopic data and the X-ray crystal structures of the complexes are reported. The cell parameters of the complexes are 1: monoclinic, P21/c, a = 13.7393(9) Å, b = 12.0512(8) Å, c = 13.3543(9) Å, β = 107.105(2)°, V = 2113.4(2) Å3, R 1 = 0.0317, wR 2 = 0.0699; and 2.½ ethanol:monoclinic, P21/c, a = 17.607(1) Å, b = 20.826(1) Å, c = 13.5887(8) Å, β = 101.875(2)°, V = 4876.0(5) Å3, R 1 = 0.0228, wR 2 = 0.0503.

Graphical Abstract

The reaction of the potentially bidentate aroylhydrazone-based N,N-donor ligands 3-((pyridin-2-yl)methyleneamino)-2,3-dihydro-2-(pyridin-2-yl)quinazolin-4-(1H)one and N-(di(pyridin-2-yl)-methylene)benzohydrazide (NN) with [Re(CO)5Cl] in alcohol led to the isolation of the neutral complexes fac-[Re(CO)3Cl(NN)].

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Scheme 2
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Schibli R, Schubiger A (2002) Eur J Nucl Med Mol Imaging 12:3729

    Google Scholar 

  2. Alberto R, Schibli R, Egli A, Schubiger AP (1998) J Am Chem Soc 120:7987

    Article  CAS  Google Scholar 

  3. Alberto R, Schibli R, Egli A, Waibel R, Abram U, Schubiger AP (1999) Coord Chem Rev 190:901

    Article  Google Scholar 

  4. Hosseini-Monfared H, Bikas R, Sanchiz J, Lis T, Siczek M, Tucek J, Zboril R, Mayer P (2013) Polyhedron 61:45

    Article  CAS  Google Scholar 

  5. Mohan M, Gupta MP, Chandra L, Jha NK (1988) Inorg Chim Acta 61:151

    Google Scholar 

  6. Richardson DR, Ponka P (1988) Am J Hermatol 58:299

    Article  Google Scholar 

  7. Kalinowski DS, Sharpe PC, Bernhardt PV, Richardison DR (2008) J Med Chem 51:331

    Article  CAS  Google Scholar 

  8. Tamasi G, Chiasserini L, Savini L, Sega A, Cini R (2005) J Inorg Biochem 99:1347

    Article  CAS  Google Scholar 

  9. Bakir M, Hassan I, Johnson T, Brown O, Green O, Gyles C, Coley MD (2004) J Mol Struct 688:213

    Article  CAS  Google Scholar 

  10. Pouralimardan O, Chamayou AC, Janiak C, Hossein-Monfared H (2007) Inorg Chim Acta 360:1599

    Article  CAS  Google Scholar 

  11. Ward MD (2005) J Solid State Electrochem 9:778

    Article  CAS  Google Scholar 

  12. Ray A, Rizzoli C, Pilet G, Desplanches C, Garriba E, Rentschler E, Mitra S (2009) Eur J Inorg Chem, 2915

  13. Hursthouse MB, Jayaweera SAA, Quick AJ (1979) Chem Soc Dalton Trans 279

  14. Hossein-Monfared H, Alavi S, Farrokhi A, Vahedpour M, Mayer P (2011) Polyhedron 30:1842

    Article  Google Scholar 

  15. Lin S, Liu SX, Huanga JQ, Lin CC (2002) Dalton Trans 1595

  16. APEX2, SADABS, SAINT, 2010, Bruker AXS Inc., Madison, Wisconsin, USA

  17. Sheldrick GM (2008) Acta Crystallogr A 64:112

    Article  CAS  Google Scholar 

  18. Hubschle CB, Sheldrick GM, Dittrich B (2011) J Appl Cryst 44:1281

    Article  Google Scholar 

  19. Yumata NC, Habarurema G, Mukiza J, Gerber TIA, Hosten E, Taherkhani F, Nahali M (2013) Polyhedron 62:89

    Article  CAS  Google Scholar 

  20. Maria L, Moura C, Paulo A, Santos IC (2006) J Organomet Chem 691:4773

    Article  CAS  Google Scholar 

  21. Tshentu ZR, Gerber TIA, Walmsley R, Mayer P (2008) Polyhedron 27:406

    Article  CAS  Google Scholar 

  22. Gerber TIA, Tshentu ZR, Mayer P (2004) J Coord Chem 58:1271

    Article  Google Scholar 

  23. Gerber TIA, Abrahams A, Mayer P (2005) J Coord Chem 58:1387

    Article  Google Scholar 

  24. Bandoli G, Dolmella A, Gerber TIA, Mayer P, Mpinda D, Perils J, du Preez JGH (2002) J Coord Chem 55:823

    Article  CAS  Google Scholar 

  25. Allen FH, Kennard O, Watson DG, Brammer L, Orpin AG, Taylor R (1987) J Chem Soc Perkin Trans II 3

  26. K. C. Potgieter (2012) PhD Thesis, Nelson Mandela Metropolitan University, Port Elizabeth

  27. Argarwal J, Johnson RP, Li G (2011) J Phys Chem A115:2877

    Article  Google Scholar 

  28. Ng CO, Lai SW, Feng H, Yiu SM, Ko CC (2012) Dalton Trans. doi: 10.1039/c1dt/10831j

  29. Fleur NS, Hili JC, Mayr A (2009) Inorg Chim Acta 362:1571

    Article  Google Scholar 

  30. Wei L, Babich JW, Quellette W, Zubieta J (2006) Inorg Chem 45:3057

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, 6031, South Africa

    Janvier Mukiza, Thomas I. A. Gerber & Eric C. Hosten

Authors
  1. Janvier Mukiza
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Thomas I. A. Gerber
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Eric C. Hosten
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Thomas I. A. Gerber.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mukiza, J., Gerber, T.I.A. & Hosten, E.C. Coordination of Bidentate Aroylhydrazone-Based N,N-Donor Ligands to the fac-[Re(CO)3]+ Core. J Chem Crystallogr 44, 368–375 (2014). https://doi.org/10.1007/s10870-014-0524-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-014-0524-4

Keywords

Search

Navigation