Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of Aromatic Hydrazone Compounds Containing Pyrazole

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Two novel aromatic hydrazone compounds containing pyrazole group were synthesized with 1-phenylpyrazole-4-carbaldehyde and benzene hydrazine (or p-tolylhydrazine hydrochloride) as the starting materials. As-synthesized aromatic hydrazone compounds were characterized by means of 1H NMR, FT-IR, Ms and single-crystal X-ray diffraction. Results shown that two aromatic hydrazone compounds crystallizes in the monoclinic system of space group P21/n for A and Pc for B respectively.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Shoichiro Y (1999) Advancement in stereochemical aspects of Schiff base metal complexes. Coord Chem Rev 190–192:537–555

    Google Scholar 

  2. Wang YZ, Claudia I, Rivera V, Lin Q (2007) Convenient synthesis of highly functionalized pyrazolines via mild, photoactivated 1,3-dipolar cycloaddition. Org Lett 9(21):4155–4158

    Article  CAS  Google Scholar 

  3. Jin LX, Liu Z, Xia JH (2007) Actuality research of synthesis and capacity of Schiff base derived from salicylaldehyde and its ramifications. J Synth Cryst 36(3):705–710

    Google Scholar 

  4. Bastos MBR, Moreira JC, Farias PAM (2000) Adsorptives tripping voltammetrie behaviour of UO2(II) complexed with the Schiff base N,N′-ethylenebis(salicylidenimine) in aqueous 4-(2-hydroxyethyl)-1-piperazine ethanesulfonic acid medium. Anal Chim Acta 408:55–83

    Article  Google Scholar 

  5. Wagner A, Schellhammer CW, Petersen S (1966) Aryl-Δ2-pyrazolines as optical brighteners. Angew Chem 5:699–704

    Article  CAS  Google Scholar 

  6. Ren TG, Liu SY, Li GH, Zhang JL, Guo J, Li WJ, Yang LR (2012) Synthesis, spectroscopic properties and theoretical studies of bis-Schiff bases derived from polyamine and pyrazolones. Spectrochim Acta Part A 97:167–175

    Article  CAS  Google Scholar 

  7. Takeshi S, Takanori F, Yoshitaka N, Yuji H, Kenichi S, Kazuhiko K (1995) Pyrazoline dimers for hole transport materials in organic electroluminescent devices. Jpn J Appl Phys 34:3124–3127

    Article  Google Scholar 

  8. Ozdemir A, Turan-Zitouni G, Kaplancikli ZA, Revial G, Güven K (2007) Synthesis and antimicrobial activity of 1-(4-aryl-2-thiazolyl)-3-(2-thienyl)-5-aryl-2-pyrazoline derivatives. Eur J Med Chem 42:403–409

    Article  Google Scholar 

  9. Sureshan CA, Bhattacharya PK (1998) Synthesis, characterisation and homogeneous catalytic activity study of Mn(II) and Fe(III) ternary complexes. J Mol Catal A Chem 136(3):285–291

    Article  CAS  Google Scholar 

  10. Rukhsana IK, Noorul HK, Sayed HRA, Sunil TP, Raksh VJ (2001) Dimeric chiral Mn(III) Schiff base complex-catalysed enantioselective epoxidation of non-functionalised alkenes. Tetrahedron Lett 42:2915–2918

    Article  Google Scholar 

  11. Wang PF, Onozawa-Komutsuzaki N, Himeda Y, Sugihara H, Arakawa H, Kasuga K (2001) 3-(2-Pyridyl)-2-pyrazoline derivatives: novel fluorescent probes for Zn2+ ion. Tetrahedron Lett 42:9199–9201

    Article  CAS  Google Scholar 

  12. Liu SY, Ren TG, Chen HB, Li GH (2012) Synthesis and characterization of novel arylformoylpyrazole. J Henan Univ Nat Sci 42(2):154–158

    Google Scholar 

Download references

Acknowledgments

The authors gratefully thank the Development of Science and Technology Plan Projects of Henan Province, China (Grant No. 142102210559) and the Natural Science Foundation of the Education Department of Henan Province, China (Grant No. 13B150921) for financial support.

Author information

Authors and Affiliations

  1. Fine Chemistry and Engineering Research Institute, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, China

    Tiegang Ren, Yongzhe Li & Jie Wang

  2. Chemical Engineering and Technology Major, Hunan City University, Yiyang, 413000, China

    Shuyun Liu

  3. Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng, 475004, China

    Guihui Li

Authors
  1. Tiegang Ren
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shuyun Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yongzhe Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guihui Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jie Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guihui Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ren, T., Liu, S., Li, Y. et al. Synthesis and Crystal Structure of Aromatic Hydrazone Compounds Containing Pyrazole. J Chem Crystallogr 44, 346–351 (2014). https://doi.org/10.1007/s10870-014-0521-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-014-0521-7

Keywords

Search

Navigation