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Crystal Growth and Structure Determination of the New Neodymium Germanate, Na2NdGeO4(OH)

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Abstract

Single crystals of Na2NdGeO4(OH) were grown out of a molten sodium hydroxide flux and characterized by single crystal X-ray diffraction. Na2NdGeO4(OH) crystallizes in the orthorhombic space group Pnma with a = 9.4373(3) Å, b = 7.4448(2) Å, c = 6.9236(2) Å, V = 486.44(2) Å3, and Z = 4. The compound exhibits a three-dimensional crystal structure consisting of corner- and edge-shared NdO8, GeO4, and NaO7 polyhedra. The Nd3+ cation is observed in a distorted square antiprismatic coordination environment.

Graphical Abstract

The synthesis and crystal structure of a new neodymium germanate, Na2NdGeO4(OH) is reported.

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Acknowledgments

This research was supported by the National Science Foundation through grant DMR-1301757.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA

    Kendall Hughey, Jeongho Yeon & Hans-Conrad zur Loye

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  1. Kendall Hughey
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  2. Jeongho Yeon
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  3. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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Hughey, K., Yeon, J. & zur Loye, HC. Crystal Growth and Structure Determination of the New Neodymium Germanate, Na2NdGeO4(OH). J Chem Crystallogr 44, 320–323 (2014). https://doi.org/10.1007/s10870-014-0517-3

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  • DOI: https://doi.org/10.1007/s10870-014-0517-3

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