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Six Supramolecular Coordination Complexes Containing Phenoxy Pyrazole-Carboxyl Ligands

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Abstract

Six new complexes, [Co(pzpa-CH3)4Cl2] (1), [M(pzpa-CH2CH3)2Cl2] [M = Mn(2), Ni(3)], [M(cpzpa)Cl]2[M(H2O)6]·nH2O [M = Co(4) n = 2, Zn(5) n = 4] and [Zn(cpzpa)Cl]·H2Cl (6) have been synthesized by hydrothermal reactions of MCl2·4H2O (M = Co, Mn, Ni, Zn) with 2-(1H-pyrazol-3-yl)-phenoxy acetic acid (Hpzpa) and [2-(1-Carboxymethyl-1H-pyrazol-3-yl)phenoxyl acetic acid (H2cpzpa). Single-crystal X-ray analyses demonstrate that they are all mononuclear structures. These compounds were characterized by elemental analysis, IR spectroscopy and luminescence.

Graphical Abstract

Six new M(II)/pzpa, cpzpa complexes (M = Co, Mn, Ni, Zn) have been synthesized and structurally characterized. The complexes 1–6 feature mononuclear structures.

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Acknowledgments

We greatly appreciate financial support from the Fundation of Suzhou Science and Technology of Jiangsu Province of China (SYN201015), Key Laboratory of Advanced Functional Materials of Jiangsu Province of China (No. 10KFJJ002), and the start-up Grant from CSLG (No. KY2009069, KYZ2010131Z).

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Authors and Affiliations

  1. Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, 215500, Jiangsu, People’s Republic of China

    Lei Shen, Wu-Xiang Li, Qiu-Jie Xia, Jie Yang, Yun Liu, Cheng Ji, Chun-Yan Wu, Yong-Shai Zhai, Gao-Wen Yang & Qiao-Yun Li

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  1. Lei Shen
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  2. Wu-Xiang Li
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Correspondence to Gao-Wen Yang or Qiao-Yun Li.

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Shen, L., Li, WX., Xia, QJ. et al. Six Supramolecular Coordination Complexes Containing Phenoxy Pyrazole-Carboxyl Ligands. J Chem Crystallogr 43, 585–595 (2013). https://doi.org/10.1007/s10870-013-0464-4

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  • DOI: https://doi.org/10.1007/s10870-013-0464-4

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