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Crystal and Molecular Structure of Two Organic Acid–Base Salts from Nicotinamide and Aromatic Acids

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Abstract

Two crystalline organic acid–base salts (nicotinamide):(3,5-dinitrosalicylic acid) [(HL+)···(3,5-dns−), 3,5-dns− = 3,5-dinitrosalicylate] (1), and (nicotinamide):(4-nitro-phthalic acid) [(HL+)···(Hnpa−), Hnpa− = 4-nitro-hydrogenphthalate] (2) derived from nicotinamide and aromatic carboxylic acids (3,5-dinitrosalicylic acid, and 4-nitro-phthalic acid) were prepared and characterized by X-ray diffraction analysis, IR, mp, and elemental analysis. Compound 1 crystallizes in the monoclinic, space group P2(1)/c, with a = 4.7950(3) Å, b = 22.290(2) Å, c = 14.3901(13) Å, β = 104.861(2)º, V = 1486.6(2) Å3, Z = 4. Compound 2 crystallizes in the monoclinic, space group P2(1)/c, with a = 15.0173(14) Å, b = 12.9849(13) Å, c = 7.7281(6) Å, β = 111.6040(10)º, V = 1401.1(2) Å3, Z = 4. Both supramolecular architectures of the compounds 1–2 involve O–H···O/N–H···O hydrogen bonds as well as other noncovalent association. The role of these noncovalent interactions in the crystal packing is ascertained. For the presence of these weak noncovalent interactions, both compounds displayed 3D framework structure.

Graphical Abstract

Due to the weak interactions, the compound displays 3D framework structure.

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Acknowledgments

We gratefully acknowledge the financial support of the Education Office Foundation of Zhejiang Province (Project No. Y201017321) and the financial support of the Zhejiang A & F University Science Foundation (Project No. 2009FK63).

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Authors and Affiliations

  1. Tianmu College, ZheJiang A & F University, Lin’An, 311300, People’s Republic of China

    Shouwen Jin, Qianli Linhe, Mingjun Fu, Siyuan Wu & Jiaqi Ren

  2. Department of Chemistry, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Daqi Wang

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  1. Shouwen Jin
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Correspondence to Shouwen Jin.

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Jin, S., Wang, D., Linhe, Q. et al. Crystal and Molecular Structure of Two Organic Acid–Base Salts from Nicotinamide and Aromatic Acids. J Chem Crystallogr 43, 258–265 (2013). https://doi.org/10.1007/s10870-013-0413-2

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  • DOI: https://doi.org/10.1007/s10870-013-0413-2

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