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Synthesis and Crystal Structure of the Mixed Metal Coordination Framework [Co2(H2O)2(pyrazine)V4O12](H2O)2

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Abstract

The coordination framework [Co2(H2O)2(pyrazine)V4O12](H2O)2 (1) was synthesized via hydrothermal synthesis using cobalt nitrate, vanadium oxide, and pyrazine. Compound 1 crystallizes in the monoclinic space group P21/n (a = 7.172(3) Å, b = 9.907(4) Å, c = 12.211(4) Å, and β = 105.301(7)°) and contains a rare V4O12 trigonal bipyramidal double chain.

Graphical Abstract

[Co2(H2O)2(pyrazine)V4O12](H2O)2 (1) was synthesized hydrothermally from a vanadium oxide precursor, forming chains of edge-sharing distorted vanadium trigonal bipyriamids.

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Acknowledgments

Financial support from the National Science Foundation through Grant CHE-0714439 is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA

    Rachel C. Severance, Eric S. Rountree, Mark D. Smith & Hans-Conrad zur Loye

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  1. Rachel C. Severance
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  2. Eric S. Rountree
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  3. Mark D. Smith
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  4. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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Severance, R.C., Rountree, E.S., Smith, M.D. et al. Synthesis and Crystal Structure of the Mixed Metal Coordination Framework [Co2(H2O)2(pyrazine)V4O12](H2O)2 . J Chem Crystallogr 42, 997–1000 (2012). https://doi.org/10.1007/s10870-012-0347-0

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