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Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate

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Abstract

A novel silver-containing compound bis-benzylamino-silver(I) benzylcarbamate with the molecular formula of C22H26N3O2Ag and structural formula of C6H5CH2NHCOOAg(NH2CH2C6H5)2 is synthesized by the reaction of benzylamonium benzylcarbamate and silver oxide. It crystallizes in triclinic crystal system and P-1 space group with a = 5.2006(5) Å, b = 14.6298(15) Å, c = 14.7246(15) Å, α = 68.729(2)°, β = 83.507(2)°, γ = 85.412(2)°, and Z = 2. In the crystal, all of the silver atoms are two-coordinate, i.e., one silver atom symmetrically chelates with the two amino groups in two benzylamine molecules, while all the carboxylate groups only act as charge balancers. In addition, the crystal contains a large quantity of hydrogen bonds sustaining the stability of three-dimensional structure.

Index Abstract

A novel compound bis-benzylamino-silver(I) benzylcarbamate with a special molecular structure of two-coordinate is conveniently synthesized and it crystallizes in triclinic crystal system and P-1 space group with a = 5.2006(5) Å, b = 14.6298(15) Å, c = 14.7246(15) Å, α = 68.729(2)°, β = 83.507(2)°, γ = 85.412(2)°, and Z = 2.

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Acknowledgments

This project is supported by the National Natural Science Foundation of China (Grant No. 51172081). We thank the Analytical and Testing Center of Huazhong University of Science and Technology for the test of MS, FT-IR, elemental analysis, TGA and DTA. We also thank Hua Li from College of Chemistry and Molecular Science of Wuhan University for collecting and solving the X-ray structures.

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Authors and Affiliations

  1. College of Mechanical & Electrical Engineering, Wenzhou University, Wenzhou, 325000, People’s Republic of China

    Yu Cao

  2. Wuhan National Laboratory for Optoelectronics, College of Optoelectronics Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People’s Republic of China

    Jian-Guo Liu, Xiang-You Li & Xiao-Yan Zeng

  3. College of Chemistry and Molecular Science, Wuhan University, Wuhan, 430072, People’s Republic of China

    Hua Li

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  1. Yu Cao
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Correspondence to Jian-Guo Liu.

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Cao, Y., Liu, JG., Li, XY. et al. Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate. J Chem Crystallogr 42, 891–896 (2012). https://doi.org/10.1007/s10870-012-0332-7

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  • DOI: https://doi.org/10.1007/s10870-012-0332-7

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