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Synthesis and Characterization of 5-Amino-1-nitriminotetrazole and Its Salts

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Abstract

New nitrogen-rich energetic compound 5-amino-1-nitriminotetrazole (2) and its ammonium (3), hydrazinium (4) salts have been prepared. Their structures were characterized and confirmed by 1H NMR spectroscopy, IR spectroscopy, elemental analysis and ESI-MS, X-ray single-crystal diffraction. Compound 2 crystallizes in the orthorhombic Pna2(1) space group with unit cell parameters are a = 9.229(2) Å, b = 5.5271(13) Å, c = 10.295(2) Å, V = 525.1(2) Å3, Z = 4. Compound 3 crystallizes in the Monoclinic C2/c space group, its unit cell parameters are a = 25.932 (6) Å, b = 6.8844(15) Å, c = 14.006(3) Å, β = 102.052(3), V = 2445.3(10) Å3, Z = 16. Compound 4 crystallizes in the Monoclinic P2(1)/c space group with unit cell parameters are a = 7.275(3) Å, b = 14.273(5) Å, c = 6.802(2) Å, β = 97.009(5) Å, V = 701.0(4) Å3, Z = 4. Extensive hydrogen bonds of these compounds packed a 3D network. Finally, the influences of molecular structure on the properties of the new compounds were discussed.

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Notes

  1. The fraction sensitivity was tested by putting 20 ± 1 mg sample which was compressed between two steel poles at a certain pressure was hit horizontally with a 1.5 kg hammer from a switch angle. The sensitivity was evaluated by testing 50 samples at a certain condition and recorded if it’s an explosion or nonexplosion, the results were listed using explosion probability method. Under the same test condition, the greater explosion probability is, the higher the sensitivity is.

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Acknowledgments

This research was supported by the National Natural Science Foundation of China (grant nos. 21076221 and 21006117), Innovation Fund of Chinese Academy of Sciences (grant no. CXJJ-11-M52), Supporting projects (grant no. GH-125-080).

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Authors and Affiliations

  1. Graduate University of the Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Long Liu & Zengxi Li

  2. Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Long Liu, Chunlin He & Chunshan Li

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  1. Long Liu
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  2. Chunlin He
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  3. Chunshan Li
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  4. Zengxi Li
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Correspondence to Chunshan Li or Zengxi Li.

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Liu, L., He, C., Li, C. et al. Synthesis and Characterization of 5-Amino-1-nitriminotetrazole and Its Salts. J Chem Crystallogr 42, 816–823 (2012). https://doi.org/10.1007/s10870-012-0319-4

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  • DOI: https://doi.org/10.1007/s10870-012-0319-4

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