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Crystal and Molecular Structure of Two Organic Acid–Base Adducts from 2-Aminopyrimidine and Carboxylic Acids

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Abstract

Two crystalline organic acid–base adducts [(L)·(Chda), L = 2-aminopyrimidine, Chda = 1,4-cyclohexanedicarboxylic acid] (1), and (2-aminopyrimidine):(butane-1,2,3,4-tetracarboxylic acid):2H2O [(HL+)2·(Bta2−)·2H2O, Bta2− = dihydrogen butane-1,2,3,4-tetracarboxylate] derived from 2-aminopyrimidine and carboxylic acids (1,4-cyclohexanedicarboxylic acid, and butane-1,2,3,4-tetracarboxylic acid) were prepared and characterized by X-ray diffraction analysis, IR, mp, and elemental analysis. Compound 1 crystallizes in the monoclinic, space group P2(1), with a = 5.2153(5) Å, b = 18.2803(17) Å, c = 7.3409(6) Å, β = 107.9960(10)°, V = 665.62(10) Å3, Z = 2. Compound 2 crystallizes in the triclinic, space group \( P\overline{1} \), with a = 5.2455(7) Å, b = 8.4637(11) Å, c = 12.0299(15) Å, α = 97.9620(10), β = 98.954(2)°, γ = 95.1990(10), V = 519.04(12) Å3, Z = 1. Both supramolecular architectures of the compounds 1–2 involve O–H···N/N–H···O hydrogen bonds as well as CH–O interactions. The role of these noncovalent interactions in the crystal packing is ascertained. These weak interactions combined, both compounds displayed 3D framework structure.

Graphical Abstract

Due to the weak interactions, the compound displays 3D framework structure.

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Scheme 1
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Acknowledgments

We gratefully acknowledge the financial support of the Education Office Foundation of Zhejiang Province (project no. Y201017321) and the financial support of the Zhejiang A & F University Science Foundation (project no. 2009FK63).

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Authors and Affiliations

  1. Tianmu College, ZheJiang A & F University, Lin’An, 311300, People’s Republic of China

    Shouwen Jin, Shanshan Liang & Shaojun Chen

  2. Department of Chemistry, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Daqi Wang

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  1. Shouwen Jin
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Correspondence to Shouwen Jin.

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Jin, S., Wang, D., Liang, S. et al. Crystal and Molecular Structure of Two Organic Acid–Base Adducts from 2-Aminopyrimidine and Carboxylic Acids. J Chem Crystallogr 42, 759–766 (2012). https://doi.org/10.1007/s10870-012-0313-x

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