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A New Glycoluril Clip and Its Self-Association in Solid State

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Abstract

A new molecular clip C30H32N6O12 (1) derived from glycoluril has been synthesized and structurally determined by NMR, MS and X-ray diffraction analysis. The crystal belongs to an orthorhombic system, space group P 2(1)2(1)2(1), with unit cell parameters a = 13.868, b = 20.844, c = 22.990 Å, α = 90°, β = 90°, γ = 90°, V = 6,645.6 Å3, Z = 4, D c = 1.456 Mg/m3, μ = 0.228 mm−1, F(000) = 3,032, R 1 = 0.0457, wR 2 = 0.1281.

Graphical Abstract

We report a new glycoluril dimer which forms a double dimeric complex supramolecular building block and then packs in a tape-like fashion forming supramolecular polymers.

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Acknowledgments

The authors would like to express their thanks to Prof. Anxin Wu and gratefully acknowledge to Xianggao Meng for performing the X-ray crystallographic measurements.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan, 467000, People’s Republic of China

    Qiaoru Liu & Ganqing Zhao

  2. Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079, People’s Republic of China

    Qiaoru Liu & Jungang Wang

Authors
  1. Qiaoru Liu
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  2. Jungang Wang
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  3. Ganqing Zhao
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Corresponding author

Correspondence to Jungang Wang.

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Liu, Q., Wang, J. & Zhao, G. A New Glycoluril Clip and Its Self-Association in Solid State. J Chem Crystallogr 42, 727–732 (2012). https://doi.org/10.1007/s10870-012-0307-8

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  • DOI: https://doi.org/10.1007/s10870-012-0307-8

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