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A New Layered Six-Connected Network Based on Tetranuclear Copper(II) Cores

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Abstract

A new copper(II) coordination polymer [Cu4(L)4(OH)2(H2O)2](NO3)2·3H2O (1)] has been synthesized by the reaction of copper nitrate and inner-salt-type dicarboxylate ligand 1-carboxymethylpyridinium-4-carboxylate inner salt (L) and the crystal structure has been determined by single crystal X-ray diffraction analysis. The complex 1 crystallizes in the monoclinic crystal system with space group C2/c and unit cell parameters: a = 23.922(5) Å, b = 13.382(3) Å, c = 16.376(3) Å, β = 125.830(3) Å. The crystal structure analysis reveals that 1 is a 2D network with 36 topology, which contains hydroxo-bridged tetranuclear copper cores [Cu4(μ3-OH)2] as nodes with Cu···Cu edges spanned by bridging L ligands. The 2D networks are further joined together through extensive O–H···O hydrogen bonds to form a 3D framework.

Graphical Abstract

A new layered six-connected complex [Cu4(L)4(OH)2(H2O)2](NO3)2·3H2O based on tetranuclear copper(II) cores has been synthesized and characterized by single crystal X-ray diffraction analysis, which reveals the complex is a 2D network with 36 topology.

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Acknowledgments

This work was supported by the Research Project of “SUST Spring Bud” (grant no. 2008AZZ077), which are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Applied Chemistry, College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266590, People’s Republic of China

    Yong-Qing Huang, Qian Zhao, Yan-Hua Wang, Sheng-Song Ge & Qian Shao

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  1. Yong-Qing Huang
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  2. Qian Zhao
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  3. Yan-Hua Wang
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  4. Sheng-Song Ge
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  5. Qian Shao
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Correspondence to Yong-Qing Huang.

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Huang, YQ., Zhao, Q., Wang, YH. et al. A New Layered Six-Connected Network Based on Tetranuclear Copper(II) Cores. J Chem Crystallogr 42, 706–710 (2012). https://doi.org/10.1007/s10870-012-0304-y

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  • DOI: https://doi.org/10.1007/s10870-012-0304-y

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