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Iron(II) and Manganese(II) Complexes of 2-{2-(3-Carboxypyridin-2-yl)disulfanyl}pyridine-3-carboxylic acid Through C–S Bond Cleavage

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Abstract

Two psuedopolymorphs of iron(II) complexes, namely [Fe(phen)3](HL2)2·H2O (1); [Fe(phen)3](H2L2)(L2)·7H2O (2) and a manganese(II) carboxylate coordination polymer [Mn(L2)(py)2(MeOH)2] n (3) (H 2 L 2 = 2-(2-(3-carboxypyridin-2-yl)disulfanyl)pyridine-3-carboxylic acid, phen = 1,10-phenanthroline, py = pyridine) were prepared via in situ generation of H 2 L 2 through concomitant C–S bond cleavage and S–S bond formation reactions of 2-(3-methyl-1,4-dihydro-naphthalen-2-yl-sulfanyl)nicotinic acid (L1). The complex 1 has, a = 26.945(3) Å; b = 11.6895(10) Å; c = 20.708(2) Å; α = 90.00º; β = 123.228(13)º; γ = 90.00º and volume = 5456.0(12) Å3, Z = 4; the complex 2 has, a = 11.575(7) Å; b = 21.530(12) Å; c = 23.212(13) Å; α = 90.00º; β = 90.13(2)º; γ = 90.00º; volume = 5785(6) Å3; Z = 4 and the coordination polymer 3 has a = 14.7154(11) Å; b = 9.0292(11) Å; c = 20.568(2) Å; α = 90.00(4)º; β = 93.032(9)º; γ = 90.00º; volume = 2729.0(5) Å3; Z = 4.

Graphical Abstract

The crystal structure of a polymeric manganese complex of in situ generated 2-(2-(3-carboxypyridin-2-yl)disulfanyl)pyridine-3-carboxylic acid and structures of two pseudopolymorphs of a mono-nuclear iron-1,10-phenanthroline complex containing anion of this dicarboxylic acid are determined.

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Fig. 1
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Scheme 2
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Acknowledgments

The authors thank Council of Scientific and Industrial Research (New-Delhi, India) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781 039, Assam, India

    W. Marjit Singh, Bigyan R. Jali & Jubaraj B. Baruah

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  1. W. Marjit Singh
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  2. Bigyan R. Jali
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  3. Jubaraj B. Baruah
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Correspondence to Jubaraj B. Baruah.

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Marjit Singh, W., Jali, B.R. & Baruah, J.B. Iron(II) and Manganese(II) Complexes of 2-{2-(3-Carboxypyridin-2-yl)disulfanyl}pyridine-3-carboxylic acid Through C–S Bond Cleavage. J Chem Crystallogr 42, 775–782 (2012). https://doi.org/10.1007/s10870-012-0295-8

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