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Journal of Chemical Crystallography

, Volume 42, Issue 5, pp 519–523 | Cite as

Copper(II)-pyrazine-2,3-dicarboxylate Coordination Polymer with Monoethanolamine, [Cu(μ3-pzdc)(mea)] n

  • Okan Zafer Yeşilel
  • Aylin Mutlu
  • Güneş Günay
  • Necmettin Caner
  • Halis Ölmez
  • Orhan Büyükgüngör
Original Paper

Abstract

A novel Cu(II)-pyrazine-2,3-dicarboxylate complex with monoethanolamine ligand (mea), [Cu(μ3-pzdc)(mea)]n (1), has been synthesized and characterized by elemental, spectral (IR and UV–Vis.) and thermal analyses. The molecular structure of polynuclear complex has been determined by the single crystal X-ray diffraction technique. The pyrazine-2,3-dicarboxylate dianion exhibits tetradentate-μ3 bridging ligand through three carboxylate oxygens and one nitrogen atom. The complex contains two copper(II) ions that exhibit two different coordination environments with two mea, two pzdc ligands, respectively. The Cu1(II) ion is coordinated by two carboxylate oxygen atoms, two N atoms and two O atoms of symmetry related carboxylate group, forming a distorted octahedral geometry, while Cu2(II) ion is coordinated by two bidentate mea ligands and remaining two coordination sites of distorted octahedral geometry are occupied by two carboxylate oxygen atoms of neighboring Cu1 molecule. Thermal analysis property and thermal decomposition mechanism of complex have been investigated by using thermal analyses techniques (TG, DTG and DTA).

Graphical Abstract

We have synthesized and structurally characterized a novel 2D Cu(II)-pyrazine-2,3-dicarboxylate coordination polymer with monoethanolamine ligand (mea), [Cu(μ3-pzdc)(mea)] n . The pyrazine-2,3-dicarboxylate ligand exhibits tetradentate-μ3 bridging ligand through three carboxylate oxygens and one nitrogen atom. The complex contains two copper(II) ions that exhibit two different coordination environments with two mea, two pzdc ligands, respectively. The crystal packing of complex is a composite of intra- and intermolecular hydrogen bonding and C–O···π interactions.

The molecular structure of [Cu(μ3-pzdc)(mea)] n

Keywords

Polynuclear complex Pyrazine-2,3-dicarboxylate complex Monoethanolamine complex 

Notes

Acknowledgment

This work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK, No: 109T201).

References

  1. 1.
    Yaghi OM, Li H (1995) J Am Chem Soc 117:10401CrossRefGoogle Scholar
  2. 2.
    Fujita M, Kwon YJ, Washizu S, Ogura K (1994) J Am Chem Soc 116:1151CrossRefGoogle Scholar
  3. 3.
    Gao S, Ma BQ, Tao Y, Wang ZM, Liao CS, Yan CH, Xu GX (1999) Chem Lett 28:773CrossRefGoogle Scholar
  4. 4.
    James SL (2003) Chem Soc Rev 32:276CrossRefGoogle Scholar
  5. 5.
    Janiak C (2003) J Chem Soc Dalton Trans 14:2781Google Scholar
  6. 6.
    Wu SM, Li M, Xiang JF, Yuan LJ, Sun JT (2006) Acta Crystallogr E62:o2951Google Scholar
  7. 7.
    Jia HP, Li W, Ju ZF, Zhang J (2006) Eur J Inorg Chem 4264Google Scholar
  8. 8.
    Sun XZ, Sun YF, Ye BH, Chen XM (2003) Inorg Chem Commun 6:1412CrossRefGoogle Scholar
  9. 9.
    Demessence A, Rogez G, Welter R, Rabu P (2007) Inorg Chem 46:3423CrossRefGoogle Scholar
  10. 10.
    Sun XZ, Huang ZL, Wang HZ, Ye BH, Chen XM (2005) Z Anorg Allg Chem 631:919CrossRefGoogle Scholar
  11. 11.
    Gong Y, Wang T, Zhang M, Hu CW (2007) J Mol Struct 833:1CrossRefGoogle Scholar
  12. 12.
    Ching N, Pan L, Huang XY, Li J (2000) Acta Crystallgr C56:1124CrossRefGoogle Scholar
  13. 13.
    Chen BL, Mok KF, Ng SC, Drew MGB (1999) New J Chem 23:877CrossRefGoogle Scholar
  14. 14.
    Driessen WL, Chang L, Finazzo C, Gorter S, Rehorst D, Reedijk J, Lutz M, Spek AL (2003) Inorg Chim Acta 350:25CrossRefGoogle Scholar
  15. 15.
    Noguchi R, Sugie A, Hara A, Nomiya K (2006) Inorg Chem Commun 9:107CrossRefGoogle Scholar
  16. 16.
    Wang FQ, Weng DF, Zheng XJ, Zhang JJ, Ma H, Jin LP (2007) Inorg Chim Acta 360:2029CrossRefGoogle Scholar
  17. 17.
    Yeşilel OZ, Mutlu A, Büyükgüngör O (2008) Polyhedron 27:2471CrossRefGoogle Scholar
  18. 18.
    Yeşilel OZ, Mutlu A, Büyükgüngör O (2008) J Coord Chem 61:3267CrossRefGoogle Scholar
  19. 19.
    O’Connor CJ, Sinn E (1981) Inorg Chem 20:545CrossRefGoogle Scholar
  20. 20.
    Wenkin M, Devillers M, Tinant B, Declercq JP (1997) Inorg Chim Acta 258:113CrossRefGoogle Scholar
  21. 21.
    Castillo O, Beobide G, Luque A, Román P (2003) Acta Crystallogr E59:m800Google Scholar
  22. 22.
    Wang MS, Cai LZ, Zhou GW, Guo GC, Mao JG, Huang JS (2003) Acta Crystallogr E59:m212Google Scholar
  23. 23.
    O’Connor CJ, Klein CL, Majeste RJ, Trefonas LM (1982) Inorg Chem 21:64CrossRefGoogle Scholar
  24. 24.
    Xu H, Ma H, Xu M, Zhao W, Guo B (2008) Acta Crystallogr E64:m104Google Scholar
  25. 25.
    Burriel R, O’Conner CJ, Carlin RL (1985) Inorg Chem 24:3706CrossRefGoogle Scholar
  26. 26.
    Okubo T, Kondo M, Kitagawa S (1997) Synthetic Metals 85:1661CrossRefGoogle Scholar
  27. 27.
    Yin HD, Li FH, Wang CH (2007) Inorg Chim Acta 360:2797CrossRefGoogle Scholar
  28. 28.
    Yin H, Liu SX (2007) Polyhedron 26:3103CrossRefGoogle Scholar
  29. 29.
    Li XH, Shi Q, Hu ML, Xiao HP (2004) Inorg Chem Commun 7:912CrossRefGoogle Scholar
  30. 30.
    Gryz M, Starosta W, Leciejewicz J (2005) J Coord Chem 58:931CrossRefGoogle Scholar
  31. 31.
    Choi KY (2002) J Incl Phen Macr Chem 43:195CrossRefGoogle Scholar
  32. 32.
    Konar S, Manna SC, Zangrando E, Chaudhuri NR (2004) Inorg Chim Acta 357:1593CrossRefGoogle Scholar
  33. 33.
    Bi-Song Z (2005) Chinese J Struct Chem 24:478Google Scholar
  34. 34.
    Ma Y, He YK, Han ZB (2006) Acta Crystallogr E62:m2528Google Scholar
  35. 35.
    Zou JZ, Xu Z, Chen W, Lo KL, You XZ (1999) Polyhedron 18:1507CrossRefGoogle Scholar
  36. 36.
    Beobide G, Castillo O, Luque A, Garcia-Coucerio U, Garcia-Teran JP, Roman P (2006) Inorg Chem 45:5367CrossRefGoogle Scholar
  37. 37.
    Hu ML, Yuan JX, Chen F, Shi Q (2004) Acta Crystallogr C60:m186Google Scholar
  38. 38.
    Kondo M, Okubo T, Asami A, Noro S, Yoshitomi T, Kitagawa S, Ishii T, Matsuzaka H, Seki K (1999) Angew Chem Int Ed 38:1433CrossRefGoogle Scholar
  39. 39.
    Zheng XJ, Jin LP, Lu SZ (2002) Eur J Inorg Chem 12:3356CrossRefGoogle Scholar
  40. 40.
    Manna SC, Ribas J, Zangrando E, Chaudhuri NR (2007) Inorg Chim Acta 360:2589CrossRefGoogle Scholar
  41. 41.
    Castro I, Calatayud ML, Sletten J, Julve M, Lloret F (2001) Comptes Rendus de l’Académie des Sciences-Series IIC–Chemistry 4:235CrossRefGoogle Scholar
  42. 42.
    Corrêa CC, Diniz R, Chagas LH, Rodrigues BL, Yoshida MI, Teles WM, Machado FC, De Oliveira LFC (2007) Polyhedron 26:989CrossRefGoogle Scholar
  43. 43.
    Kondo M, Okubo T, Asami A, Noro SI, Yoshitomi T, Kitagawa S, Ishii T, Matsuzaka H, Seki K (1999) Angew Chem Int Ed 38:140CrossRefGoogle Scholar
  44. 44.
    Sheldrick GM (1997) SHELXS–97 and SHELXL–97. Program for refinement of crystal structures. University of Göttingen, GermanyGoogle Scholar
  45. 45.
    Stoe & Cie (2002) X-area (Version 1.18) and X-Red32 (Version 1.04). Stoe&Cie, Darmstadt, Germany, 2001Google Scholar
  46. 46.
    Macrae CF, Edgington PR, McCabe P, Pidcock E, Shields GP, Taylor R, Towler M, van de Streek J (2006) J Appl Crystallogr 39:453CrossRefGoogle Scholar
  47. 47.
    Farrugia LJ, Win GX (1999) Suite for single crystal small molecule crystallography. J Appl Crystallogr 32:837CrossRefGoogle Scholar
  48. 48.
    Nakamoto K (1997) Infrared and raman spectra of inorganic and coordination compounds, 5th edn. Wiley Interscience, New York, pp 59–62Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Okan Zafer Yeşilel
    • 1
  • Aylin Mutlu
    • 1
  • Güneş Günay
    • 1
  • Necmettin Caner
    • 1
  • Halis Ölmez
    • 2
  • Orhan Büyükgüngör
    • 3
  1. 1.Department of Chemistry, Faculty of Arts and SciencesEskişehir Osmangazi UniversityEskişehirTurkey
  2. 2.Department of Chemistry, Faculty of Arts and SciencesOndokuz Mayıs UniversitySamsunTurkey
  3. 3.Department of Physics, Faculty of Arts and SciencesOndokuz Mayıs UniversitySamsunTurkey

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