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A 2D Network in Co-Crystal (1:1) Based on trans-[PtBr2(Acetoxime)2] and 18-Crown-6

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Abstract

A 1:1 co-crystal of trans-[PtBr2(acetoxime)2] and 18-crown-6 has been obtained by a slow-evaporation of the equimolar mixture of trans-[PtBr2(acetoxime)2] and the crown ether. The compound crystallizes in the triclinic space group \( P\,\bar{1} \), with unit cell parameters a = 7.4765(2) Å, b = 9.5044(2) Å, c = 10.1591(3) Å, α = 83.687(1)°, β = 70.847(1)°, γ = 79.773(1)°, Z = 1. trans-[PtBr2(acetoxime)2] is assembled with 18-crown-6 into a 2D network structure by interactions between the oxygen atoms of 18-crown-6 and the hydroxylic and methyl hydrogen atoms of the oxime ligands.

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Acknowledgments

The authors are much obliged to Russian Fund for Basic Research for grant 09-03-00065-a and Saint-Petersburg State University for a research grant (2011–2013).

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Authors and Affiliations

  1. Department of Chemistry, St. Petersburg State University, Stary Petergof, Russian Federation, 198504

    Evgeny Yu. Bulatov, Tatiana G. Chulkova & Vadim Yu. Kukushkin

  2. Department of Chemistry, University of Eastern Finland, P.O. Box 111, FI-80101, Joensuu, Finland

    Matti Haukka

Authors
  1. Evgeny Yu. Bulatov
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  2. Tatiana G. Chulkova
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  3. Matti Haukka
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  4. Vadim Yu. Kukushkin
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Correspondence to Tatiana G. Chulkova.

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Bulatov, E.Y., Chulkova, T.G., Haukka, M. et al. A 2D Network in Co-Crystal (1:1) Based on trans-[PtBr2(Acetoxime)2] and 18-Crown-6. J Chem Crystallogr 42, 352–355 (2012). https://doi.org/10.1007/s10870-011-0252-y

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  • DOI: https://doi.org/10.1007/s10870-011-0252-y

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