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Synthesis and Crystal Structures of the Coordination Polymers Pb(PYTAC)2 and Pb2(PYTAC)3(NO3) (PYTAC = 2-(pyridin-4-yl)thiazole-5-carboxylate)

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Abstract

Two lead coordination compounds, Pb(PYTAC)2 (1), and Pb(PYTAC)2(NO3) (2), were grown as single crystals via hydrothermal synthesis (PYTAC = 2-(4-pyridyl) thiazole-4-carboxylate). Both compounds have been identified via single crystal X-ray diffraction. Coordination polymer 1 crystallizes in a triclinic space group P-1 (a = 5.5097(4) Å, b = 7.2822(5) Å, c = 11.3134(8) Å, α = 103.5580(10)°, β = 99.4330(10)°, γ = 97.1050(10)°), and forms 2-D layers parallel to the crystallographic (ac) plane. Coordination polymer 2 crystallizes in a triclinic space group P-1 (a = 9.8102(5) Å, b = 10.5972(6) Å, c = 14.8076(8) Å, α = 91.9350(10)°, β = 100.8050(10)°, γ = 103.1350(10)°), and forms an infinite 1-D chains along the a axis.

Graphical Abstract

2-(4-pyridyl) thiazole-4-carboxylate (PYTAC) contains a number of potential coordination sites to which a lead cation can coordinate, allowing study of the preferential binding character of this ion.

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Acknowledgments

Financial support from the National Science Foundation through Grant CHE-0714439 is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA

    Rachel C. Severance, Ankur M. Patel, Mark D. Smith & Hans-Conrad zur Loye

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  1. Rachel C. Severance
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  2. Ankur M. Patel
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  3. Mark D. Smith
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  4. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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Severance, R.C., Patel, A.M., Smith, M.D. et al. Synthesis and Crystal Structures of the Coordination Polymers Pb(PYTAC)2 and Pb2(PYTAC)3(NO3) (PYTAC = 2-(pyridin-4-yl)thiazole-5-carboxylate). J Chem Crystallogr 42, 258–262 (2012). https://doi.org/10.1007/s10870-011-0234-0

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  • DOI: https://doi.org/10.1007/s10870-011-0234-0

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