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Synthesis and Crystal Structures of the Mixed Ligand Coordination Polymers [Co2(N3)2(BZA)4(H2O)]·EtOH, Cu(N3)(BZA)2(H2O), and Cu(N3)(SUCC)(H2O)2 (N3 = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene, BZA = benzoate, and SUCC = succinate)

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Abstract

The coordination polymers [Co2(N3)2(BZA)4(H2O)]·EtOH (1) and Cu(N3)(BZA)2(H2O) (2) were synthesized via room temperature diffusion layering using 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (N3), cobalt nitrate, copper acetate, and sodium benzoate (NaBZA). Compound 1 crystallizes in the monoclinic C2/c space group with unit cell dimensions of a = 15.8952(6) Å, b = 13.9127(6) Å, c = 24.2984(10) Å, and β = 100.595(1)°. Compound 2 crystallizes in the orthorhombic Pna21 space group with unit cell dimensions of a = 22.211(3) Å, b = 5.9543(7) Å, and c = 18.038(2) Å. The coordination polymer Cu(N3)(SUCC)(H2O)2 (3) was synthesized via room temperature diffusion layering using 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (N3), copper acetate, and sodium succinate (NaSUCC). Compound 3 crystallizes in the monoclinic P21/n space group with unit cell dimensions of a = 8.8148(7) Å, b = 8.7643(7) Å, c = 11.7758(9) Å, and β = 102.6990(10)°.

Graphical Abstract

Three mixed ligand coordination polymers, [Co2(N3)2(BZA)4(H2O)]·EtOH (1), Cu(N3)(BZA)2(H2O) (2), and Cu(N3)(SUCC)(H2O)2 (3) were synthesized via room temperature diffusion layering using 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (3).

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Acknowledgments

Financial support from the National Science Foundation through Grant CHE-0714439 and Grant CHE-0714555 is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA

    Rachel C. Severance, Mark D. Smith, Shae Anne Vaughn & Hans-Conrad zur Loye

  2. Department of Chemistry, Francis Marion University, Hwy 301 N, Florence, SC, 29502, USA

    LeRoy Peterson Jr.

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  1. Rachel C. Severance
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  2. Mark D. Smith
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  3. Shae Anne Vaughn
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  5. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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Severance, R.C., Smith, M.D., Vaughn, S.A. et al. Synthesis and Crystal Structures of the Mixed Ligand Coordination Polymers [Co2(N3)2(BZA)4(H2O)]·EtOH, Cu(N3)(BZA)2(H2O), and Cu(N3)(SUCC)(H2O)2 (N3 = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene, BZA = benzoate, and SUCC = succinate). J Chem Crystallogr 42, 141–149 (2012). https://doi.org/10.1007/s10870-011-0215-3

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