Abstract
The nickel(II) complex Ni[C5H4N–C(CH3)=N–N=C(O)–C6H5]2 (1), containing the potentially tridentate Schiff base like hydrazone ligand (LH) which is the 1:1 condensation product of benzhydrazide and 2-acetylpyridine, was prepared and characterized by IR and UV–Vis spectra, thermal analysis and single crystal X-ray diffraction measurements. Structural investigation shows that the molecule prefers a monoclinic lattice, having space group Cc, a = 10.248(6), b = 19.692(11), c = 12.281(7) Å, β = 91.523(10)º, Z = 4. The central Ni atom is in N4O2 coordination sphere developed with the NNO donor sets of the two independently Schiff base like hydrazone ligands with the two Ni–N(pyridine) bonds being significantly longer than the two Ni–N(imino) bonds, 2.096(6), 2.105(6) versus 1.972(6), 2.008(6) Å. The two Ni(II) amide-O bond distances of the chelating ligands are 2.090(6) and 2.092(6) Å respectively.
Graphical Abstract
The Ni(II) complex, Ni[C5H4N–C(CH3)=N–N=C(O)–C6H5]2 containing a hydrazone ligand has been generated into which the central Ni(II) atom belongs to a N4O2 coordination environment arised from the enol form of the ligand. It possesses a distorted octahedral geometry.
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References
Brudenell SJ, Spiccia L, Tiekink ERT (1996) Inorg Chem 35:1974
Whitmore BC, Eisenberg R (1983) Inorg Chem 22:1
Wieghardt K, Tolksdorf I, Herrmann W (1985) Inorg Chem 24:1230
Lee DH, Murthy NN, Karlin KD (1996) Inorg Chem 35:804
Zacharias PS, Ramachandraiah A (1985) Polyhedron 4:1013
You Z-L, Zhu H-L, Liu W-SZ (2004) Anorg Allg Chems 630:1617
You Z-L, Zhu H-LZ (2004) Anorg Allg Chem 630:2754
Golcu A, Tumer M, Demirelli H, Wheatley RA (2005) Inorg Chim Acta 358:1785
Choudhury CR, Dey SK, Mondal N, Mitra S, Mahalli SOG, Malik KMAJ (2002) J Chem Crystallogr 31:57
Suez IHA, Pehkonen SO, Hoffmann MR (1994) Sci Technol 28:2080
Patai S (1970) The Chemistry of Carbon–Nitrogen Double Bond, Interscience, New York
Galiz JC, Rub JC, Edger J (1955) Nature 34:176
Iskander MF, Zayan SE, Khalifa MA, Elsayed LJ (1974) Inorg Nucl Chem 36:556
Marchent JR, Clothia DSJ (1970) Med Chem 13:335
Dilworth JR (1976) Coord Chem Rev 21:29
Sridhar S, Saravanan M, Ramesh A (2001) Eur J Med Chem 36:615
Bottari B, Maccari R, Monforte F, Ottana R, Rotondo E, Vigorita M (2000) Bioorg Med Chem Lett 10:657
Sangeetha NR, Pal S, Pal S (2000) Polyhedron 19:2713
Naskar S, Biswas S, Mishra D, Adhikary B, Falvello LR, Soler T, Schwalbe CH, Chattopadhyay SK (2004) Inorg Chim Acta 357:4257
Berkessel A, Bolte M, Nemann T, Seidel L (1996) Chem Ber 129:1183
Lancaster JR (ed) (1988) The bioinorganic chemistry of nickel, VCH, New York
Parashar RK, Sharma RC, Kumar A, Mohan G (1988) Inorg Chim Acta 151:201
Beley M, Collin JP, Rupert R, Sauvage JPJ (1986) J Am Chem Soc 108:7461
Holm RH, Everett Jr, Chakravorty GW (1966) A Prog Inorg Chem 7:83
Costes JP, Dahan F, Dominguez-Vera JM, Laurent JP, Ruiz J, Sotiropoulos J (1994) Inorg Chem 33:3908
Sen S, Talukder P, Rosair G, Mitra S (2005) Struct Chem 16:605
Sheldrick GM (1990) SHELXL-PLUS, Siemens X-ray Analytical Instruments Inc., Madison
Sheldrick GM (1993) SHELXL 93: Program for Crystal Structure Refinement, Univ. of Goettingen, Germany
Nakamoto K (1978) Infrared and Raman spectra of inorganic and coordination compounds, 3rd edn, Wiley, New York
Lever ABP (1984) Inorganic electronic spectroscopy, 2nd edn. Elsevier, Amsterdam
Felicio RC, Canalheiro ETG, Dockal ER (2001) Polyhedron 20:261
Zolezzi S, Decinti A, Spodine E (1999) Polyhedron 18:897
Malik KMA, Mitra S, Singh RJKJ (1999) J Chem Crystallogr 29:877
Squattrio PJ, Iwamoto T, Nishikiori S (1996) J Chem Soc, Chem Comm. p 2665
Pariya C, Ghosh S, Ghosh A, Mukherjee M, Mukherjee AK, Chaudhuri NR (1995) J Chem Soc, Dalton Trans. p 337
Pariya C, Ghosh A, Chaudhuri NR, Ghosh S, Mukherjee M, Mukherjee AK (1996) Polyhedron 15:1643
Mondal N, Mitra S, Gramilich V, Ghodsi SO, Malik KMA (2001) Polyhedron 20:135
Acknowledgments
The authors gratefully acknowledge financial support from the National Science Council of Taiwan. JHH would also like to thank the National Changhua University of Education for the purchase of the CAD-4 diffractometer system.
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Datta, A., Chuang, NT. & Huang, JH. Synthesis and Structural Characterization of a Nickel(II) Complex with Unsymmetrical NNO-Donor Schiff Base like Hydrazone Ligand. J Chem Crystallogr 41, 1780–1784 (2011). https://doi.org/10.1007/s10870-011-0173-9
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DOI: https://doi.org/10.1007/s10870-011-0173-9