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Syntheses, Crystal Structures and Physical Properties of Cd(II) and Mn(II) Complexes with Trans-1,2-di(4-pyrindyl)ethylene and P-(carboxyl-methyloxy)-benzenecarboxylic Acid

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Abstract

Two complexes [Cd2(dpe)3(H2O)8]·(dpe)·(hssal)2·(H2O)2 1, [Mn(dpe)2(Hpcmb)2·(H2O)2] 2, (dpe = trans-1,2-di(4-pyrindyl)ethylene; H2hssal = sulphosalicylic acid; H2pcmb = p-(carboxyl-methyloxy)-benzenecarboxylic acid) has been prepared, and was characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction. Structure indicates in complex 1 that Cd(II) is a distorted octahedral coordination geometry. The hssal2− anions are localized between 2-D sheets {[Cd(dpe)2(H2O)4]2+(dpe)}n and {{[Cd(dpe)2(H2O)4]2+}n as count anions and bridge to further connect these 2-D sheets through hydrogen bond O–H···O to form 3-D structure. The complex 2 is a single molecule structure. In 2, Each Mn(II) atom is six-coordinated with a distorted octahedral coordination geometry. The single molecule units are extended into three-dimensional structure via π–π, hydrogen bonding interactions. The thermogravimetric behavior and luminescent property of complex 1 were investigated.

Graphical Abstract

Two complexes, [Cd2(dpe)3(H2O)8]·(dpe)·(hssal)2·(H2O)2 1, [Mn(dpe)2(Hpcmb)2(H2O)2] 2 have been prepared, and were characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction. Structures indicate that two complexes are extended into three-dimensional structure via π–π, C–H···π and hydrogen bonding interactions. The thermogravimetric behavior and luminescent property of complex 1 were investigated.

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Acknowledgments

The authors are grateful to the University Science Foundation of An Hui Provience (Grant No. KJ2011Z271) and The Applied Chemistry Key Constructing Subject of An Hui Education Department (200802187C) for financial support of this study.

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Authors and Affiliations

  1. Department of Chemistry and Life Science, Chu Zhou University, Chu Zhou, 239012, An Hui Province, China

    Gang Wu, Zhen-Feng Liu, Li Guo & Hui-Hui Li

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  1. Gang Wu
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  2. Zhen-Feng Liu
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  3. Li Guo
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  4. Hui-Hui Li
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Correspondence to Gang Wu.

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Wu, G., Liu, ZF., Guo, L. et al. Syntheses, Crystal Structures and Physical Properties of Cd(II) and Mn(II) Complexes with Trans-1,2-di(4-pyrindyl)ethylene and P-(carboxyl-methyloxy)-benzenecarboxylic Acid. J Chem Crystallogr 41, 1673–1679 (2011). https://doi.org/10.1007/s10870-011-0156-x

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  • DOI: https://doi.org/10.1007/s10870-011-0156-x

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