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Synthesis and Crystal Structure of Thiazole Orange Derivative

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Abstract

The title compound of Thiazole Orange derivative was synthesized by the reaction of benzothiazolium and 4-methyl quinoline salts, which was determined by 1HNMR and MS. A crystalline hydrate of thiazole orange derivative was obtained when the crystal formed and characterized by single-crystal X-ray diffraction. The crystal belongs to the Triclinic system, and the cell parameters of space group P-1 were a = 10.162(2) Å, b = 10.501(2) Å, c = 11.040(2) Å, α = 92.17(3)o, β = 117.10(3)o, γ = 92.28(3)o, V = 1045.9(4) Å3, Z = 2, Dc = 1.380 mg/m−3, μ = 0.2 mm−1, F(000) = 460, and the final R = 0.0625 and wR = 0.1862 for 3658 observed reflections (I > 2σ(I)). The two aromatic rings linked by the methylene bridged chain are a coplanar structure.

Graphical Abstract

The title compound of Thiazole Orange derivative with crystal water was synthesized and characterized by 1HNMR, MS, and single-crystal X-ray diffraction

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Acknowledgments

The authors are grateful for financial support from the National Natural Science Foundation of China (No. 20772090, 21072147), Key Project of Science and Technology Committee of Tianjin, China (No.08JCZDJC18200, 10JCYBJC10500).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China

    Xuening Fei & Yingchun Gu

  2. Department of Material Science and Engineering, Tianjin Institute of Urban Construction, No. 26 Jinjing Road, Xiqing District, Tianjin, 300384, China

    Xuening Fei, Yingchun Gu, Yunquan Lan, Bin Shi & Baolian Zhang

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  1. Xuening Fei
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  2. Yingchun Gu
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  3. Yunquan Lan
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Correspondence to Xuening Fei.

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Fei, X., Gu, Y., Lan, Y. et al. Synthesis and Crystal Structure of Thiazole Orange Derivative. J Chem Crystallogr 41, 1232–1236 (2011). https://doi.org/10.1007/s10870-011-0080-0

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