Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structure and Thermal Behavior of a New Polynitrile N,N,N′,N′-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new polynitrile, N,N,N′,N′-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine, was synthesized by the nucleophilic addition reaction of 1,4-bis(3-aminopropyl)piperazine and acrylonitrile for the first time. The title compound was characterized by elemental analysis, IR spectrum, and its crystal structure determined by X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system with space group P2 1/c and a = 8.6195(12), b = 9.300(14), c = 16.221(2) Å, β = 97.824(2)°, V = 1288.2(3) Å3, D c  = 1.064 g cm−3, M r  = 412.59, Z = 2, F(000) = 448, μ = 0.067 mm−1. The TG–DTA analysis revealed that the title compound possesses relatively good thermal stability under 220 °C.

Graphical Abstract

A new polynitrile, N,N,N′,N′-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine, was synthesized and characterized by elemental analysis, IR spectrum, TG–DTA, and X-ray single-crystal diffraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Addis D, Enthaler S, Junge K, Wendt B, Beller M (2009) Tetrahedron Lett 50:3654

    Article  CAS  Google Scholar 

  2. Hu GQ, Xie SQ, Huang WL (2007) Chin Chem Lett 18:124

    Article  CAS  Google Scholar 

  3. Su XC, Zhou ZF, Li SQ, Lin HK, Zhu SR, Sun HW, Leng XB, Chen RD (1999) Acta Scientiarum Naturalium Universitatis Nankaiiensis 3:118

    Google Scholar 

  4. Nie GC (2004) Photogr Sci Photochem 22:293

    CAS  Google Scholar 

  5. Tai XS, Yin XH, Tan MY (2003) Chin J Struct Chem 22:411

    CAS  Google Scholar 

  6. Zhou J, Daik J, Bian GQ, Li CY (2009) Coord Chem Rev 253:1221

    Article  CAS  Google Scholar 

  7. Almesaker A, Scott JL, Spiccia L, Strauss CR (2009) Tetrahedron Lett 50:1847

    Article  CAS  Google Scholar 

  8. Iida S, Togo H (2007) Tetrahedron 63:8274

    Article  CAS  Google Scholar 

  9. Xu XY, Xu TT, Wang DQ, Gao J, Li DN (2007) Acta Cryst E63:O103

    CAS  Google Scholar 

  10. Xu XY, Li DN, Gao J, Xu TT, Zhang WY, Zhang C, Zhang ZJ (2005) Ind Miner Process 9:16

    Google Scholar 

  11. Gao J, Xu XY, Yang XJ, Lu LD, Wang X (2005) Chem Reag 27:173

    CAS  Google Scholar 

  12. Xu XY, Wei X, Lin Y, Zhu CZ, Guo M, Xiao MJ (2004) J Huaihai Inst Technol 13:35

    CAS  Google Scholar 

  13. Xu XY, Wei X, Gao J, Lin Y, Zhu CZ, Guo M, Xiao MJ (2004) J Huaihai Inst Technol 13:38

    CAS  Google Scholar 

  14. Xu XY, Sun GJ, Gao J, Zhang XY, Tang YL (2003) J Huaihai Inst Technol 12:32

    CAS  Google Scholar 

  15. Gao J, Xu XY, Zhang XY, Tang YL (2003) J Huaihai Inst Technol 12:39

    CAS  Google Scholar 

  16. Gao J, Xu XY, Yang XJ, Lu LD, Wang X (2003) Mod Chem Ind 23:32

    CAS  Google Scholar 

  17. Gao J, Xu XY, Tang YL, Zhang XY (2003) Ind Min Process 2:23

    Google Scholar 

  18. Jin YC, Gao J, Xu XY, Li SA (2005) Chem Reag 27:485

    CAS  Google Scholar 

Download references

Acknowledgments

This study is supported by the Major Project for Fundamental Research of Jiangsu Provincial Educational Committee of China (no. 07KJA150011), the Opened Funds of Jiangsu Key Laboratory of Marine Biotechnology of Huaihai Institute of Technology (2009HS06) and by Qing Lan Project of Jiangsu Province (2008).

Author information

Authors and Affiliations

  1. Huaiyin Institute of Technology, 223003, Huaian, People’s Republic of China

    Xing-You Xu

  2. Chemical Engineering Department, Huaihai Institute of Technology, 222005, Lianyungang, People’s Republic of China

    Rui-Bo Xu, Yu-Min Zhou, Wei-Xing Ma, Yu-Ping Huang & Chun-Mei Xu

  3. Laboratory of Soft Chemistry and Functional Materials, Nanjing University of Science & Technology (Ministry of Education), 210094, Nanjing, People’s Republic of China

    Rui-Bo Xu, Xing-You Xu & Xu-Jie Yang

  4. Department of Chemical Engineering, Shandong Liaocheng University, 252059, Liaocheng, People’s Republic of China

    Da-Qi Wang

Authors
  1. Rui-Bo Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xing-You Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu-Min Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xu-Jie Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Wei-Xing Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Da-Qi Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yu-Ping Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Chun-Mei Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xing-You Xu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xu, RB., Xu, XY., Zhou, YM. et al. Synthesis, Crystal Structure and Thermal Behavior of a New Polynitrile N,N,N′,N′-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine. J Chem Crystallogr 41, 1190–1194 (2011). https://doi.org/10.1007/s10870-011-0069-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0069-8

Keywords

Search

Navigation