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Synthesis, Crystal Structure, Spectral and Thermal Studies of (E)-4-Dimethamino[(1-phenylethyl)iminomethyl]benzyne

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Abstract

Schiff-base compound (E)-4-dimethamino[(1-phenylethyl)iminomethyl]benzyne was synthesized and characterized by elemental analyses (CHN), FT-IR and 1H-NMR spectroscopic techniques and thermogravimetric analyses (TG). Crystal structure of the title compound was obtained by single crystal X-ray diffraction. The title compound crystallizes in the monoclinic space group P21 with unit cell parameters: a = 8.5283(2), b = 6.0699(2), c = 13.6997(4) Ǻ, β = 91.471(2)°, V = 708.94(4) Ǻ3 and Z = 2.

Graphical Abstract

Schiff-base compound (E)-4-dimethamino[(1-phenylethyl)iminomethyl]benzyne was synthesized and characterized by elemental analyses (CHN), FT-IR and 1H-NMR spectroscopic techniques and thermogravimetric analyses (TG).

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Acknowledgments

We acknowledge the Golestan University (GU), Damghan University (DU) for partial support of this work, The University of Burdwan (UB) for TG and the institutional research plan No. AVOZ10100521 of the Institute of Physics and the project P204/11/0809 of the Grant Agency of the Czech Republic.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    Aliakbar Dehno Khalaji & Sepideh Maghsodlou Rad

  2. School of Chemistry, Damghan University, P.O. Box 36715-364, Damghan, Iran

    Gholamhossein Grivani

  3. Institute of Physics of the ASCR, v.v.i, Na Slovance 2, 182 21, Prague 8, Czech Republic

    Karla Fejfarova & Michal Dusek

  4. Department of Chemistry, The University of Burdwan, Burdwan, West Bengal, India

    Debasis Das

Authors
  1. Aliakbar Dehno Khalaji
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  2. Sepideh Maghsodlou Rad
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  3. Gholamhossein Grivani
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  4. Karla Fejfarova
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  5. Michal Dusek
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  6. Debasis Das
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Correspondence to Aliakbar Dehno Khalaji.

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Khalaji, A.D., Maghsodlou Rad, S., Grivani, G. et al. Synthesis, Crystal Structure, Spectral and Thermal Studies of (E)-4-Dimethamino[(1-phenylethyl)iminomethyl]benzyne. J Chem Crystallogr 41, 1145–1149 (2011). https://doi.org/10.1007/s10870-011-0060-4

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  • DOI: https://doi.org/10.1007/s10870-011-0060-4

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