Skip to main content
SpringerLink
Log in

Synthesis and Structural Characterization of a Nickel(II) Complex with Unsymmetrical NNO-Donor Schiff Base Ligand

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The nickel(II) complex, Ni[C5H4N–CH=N–N=C(O)–C6H5]2 (1) containing a N,N,O-donor hydrazone ligand, which is the 1:1 condensation product of benzhydrazide and pyridine-2-carboxaldehyde has been synthesized and characterized by single crystal X-ray diffraction technique, spectral study and room-temperature magnetic moments. Structural investigation shows that 1 crystallizes to a monoclinic system, having space group P2(1)/c, a = 11.221(4), b = 8.893(3), c = 23.026(8) Å, β = 90.605(14)°, and Z = 4. The central nickel atom is in an N4O2 coordination sphere developed with the NNO donor sets of the two independently hydrazone ligands. The Ni–N (pyridine), Ni–N (imine) and Ni–O (enolate) bond distances are 2.144(2) and 2.128(2); 1.980(2) and 1.985(2); 2.0782(17) and 2.1106(17) Å, respectively. The effective magnetic moment (μ eff) value of 1 is found to be 3.10 B.M. at 300 K.

Graphical Abstract

The Ni(II) complex, Ni[C5H4N–CH=N–N=C(O)–C6H5]2 containing a hydrazone ligand has been generated into which the central Ni(II) atom belongs to a N4O2 coordination environment arised from the enol form of the ligand. It possesses a distorted octahedral geometry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Pouralimardan O, Chamayou AC, Janiak C, Monfared HH (2007) Inorg Chim Acta 360:1599

    Article  CAS  Google Scholar 

  2. Galić N, Perić B, Kojić-Prodić B, Cimerman Z (2001) J Mol Struct 559:187

    Article  Google Scholar 

  3. Bu XH, Gao YX, Chen W, Liu H, Zhang RH (2001) J Rare Earths 19:70

    Google Scholar 

  4. Yang ZY, Yang RD, Cai LP (2000) Chin J Appl Chem 17:371

    CAS  Google Scholar 

  5. Yang R, He SY, Wu WT, Shi QZ, Wang DQ (2005) Chem J Chin Univ 26:401

    CAS  Google Scholar 

  6. Fun HK, Sivakumar K, Lu ZL, Duan CY, Tian YP, You XZ (1996) Acta Crystallogr C52:1505

    CAS  Google Scholar 

  7. Gallego M, Valcarcel M, Garcia-Vargas M (1983) Analyst 108:92

    Article  CAS  Google Scholar 

  8. Bale MN, Dave DP, Sawant AD (1995) Talanta 42:1291

    Article  CAS  Google Scholar 

  9. Cañizares P, Luque de Castro MD (1994) Anal Chim Acta 295:59

    Article  Google Scholar 

  10. Babaiah O, Rao CK, Reddy TS, Reddy VK (1996) Talanta 43:551

    Article  CAS  Google Scholar 

  11. Sangeetha NR, Pal S, Pal S (2000) Polyhedron 19:2713

    Article  CAS  Google Scholar 

  12. Plass W, Pohlmann A, Yozgatli HP (2000) J Inorg Biochem 80:181

    Article  CAS  Google Scholar 

  13. Dinda R, Sengupta P, Ghosh S, Mak TCW (2002) Inorg Chem 41:1684

    Article  CAS  Google Scholar 

  14. Raveendran R, Pal S (2005) Polyhedron 24:57

    Article  CAS  Google Scholar 

  15. Naskar S, Biswas S, Mishra D, Adhikary B, Falvello LR, Soler T, Schwalbe CH, Chattopadhyay SK (2004) Inorg Chim Acta 357:4257

    Article  CAS  Google Scholar 

  16. Khalil TE, Labib L, Iskander MF (1994) Polyhedron 13:2569

    Article  CAS  Google Scholar 

  17. Sheldrick GM (1990) SHELXL-PLUS. Siemens X-ray Analytical Instruments Inc., Madison

    Google Scholar 

  18. Sheldrick GM (1993) SHELXL 93: program for crystal structure refinement. University of Gottingen, Gottingen

    Google Scholar 

  19. Nakamoto K (1978) Infrared and Raman spectra of inorganic and coordination compounds, 3rd edn. John Wiley & Sons, New York

    Google Scholar 

  20. Lever ABP (1984) Inorganic electronic spectroscopy, 2nd edn. Amsterdam, Elsevier

    Google Scholar 

  21. Felicio RC, Canalheiro ETG, Dockal ER (2001) Polyhedron 20:261

    Article  CAS  Google Scholar 

  22. Malik KMA, Mitra S, Singh RJK (1999) J Chem Cryst 29:877

    Article  CAS  Google Scholar 

  23. Squattrio PJ, Iwamoto T, Nishikiori S (1996) J Chem Soc Chem Comm 2665

  24. Pariya C, Ghosh S, Ghosh A, Mukherjee M, Mukherjee AK, Chaudhuri NR (1995) J Chem Soc Dalton Trans 337

  25. Pariya C, Ghosh A, Chaudhuri NR, Ghosh S, Mukherjee M, Mukherjee AK (1996) Polyhedron 15:1643

    Article  CAS  Google Scholar 

  26. Mondal N, Mitra S, Gramilich V, Ghodsi SO, Malik KMA (2001) Polyhedron 20:135

    Article  CAS  Google Scholar 

Download references

Acknowledgments

KD and CS would like to thank to CSIR (Council of Science and Industrial Research, New Delhi, India, 2337/09/EMR-II) for the grant. AD and NR express their appreciation to the National Research Foundation (NRF), South Africa for providing the X-ray diffractometer facility.

Author information

Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, 700032, India

    Kuheli Das & Chittaranjan Sinha

  2. Department of Chemistry, University of Zululand, Private Bag X1001, KwaDlangezwa, 3994, Republic of South Africa

    Amitabha Datta & Neerish Revaprasadu

Authors
  1. Kuheli Das
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chittaranjan Sinha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Amitabha Datta
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Neerish Revaprasadu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Amitabha Datta.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Das, K., Sinha, C., Datta, A. et al. Synthesis and Structural Characterization of a Nickel(II) Complex with Unsymmetrical NNO-Donor Schiff Base Ligand. J Chem Crystallogr 41, 1032–1035 (2011). https://doi.org/10.1007/s10870-011-0040-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0040-8

Keywords

Search

Navigation