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Synthesis and Crystal Structures of Copper(II) Complexes Derived from 5-Methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate and (2-Morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine

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Abstract

A pair of copper(II) complexes, [CuL1(ONO2)(OH2)] 1 and [CuBrL2N3] 2, where L1 is 5-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate, and L2 is (2-morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine, have been synthesized and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. Complex 1 crystallizes in the monoclinic space group P21/c, with a = 10.496(2), b = 19.113(3), c = 8.586(2) Å, β = 105.186(10)°. Complex 2 crystallizes in the monoclinic space group C2/c, with a = 16.606(3), b = 7.357(2), c = 26.043(5) Å, β = 94.996(2)°. The Cu atom in each complex is five-coordinate in a square pyramidal geometry.

Graphical Abstract

The synthesis and crystal structures of a pair of copper(II) complexes with Schiff bases have been presented.

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References

  1. Biswas M, Pilet G, Tercero J, El Fallah MS, Mitra S (2009) Inorg Chim Acta 362:2915

    Article  CAS  Google Scholar 

  2. Rao PV, Rao CP, Wegelius EK, Rissanen K (2003) J Chem Crystallogr 33:139

    Article  CAS  Google Scholar 

  3. Pal S, Pal S (2000) J Chem Crystallogr 30:329

    Article  CAS  Google Scholar 

  4. Alyea EC, Dee TD, Ferguson G (1985) J Chem Crystallogr 15:29

    CAS  Google Scholar 

  5. Borisova NE, Reshetova MD, Ustynyuk YA (2007) Chem Rev 107:46

    Article  CAS  Google Scholar 

  6. Che CM, Huang JS (2003) Coord Chem Rev 242:97

    Article  CAS  Google Scholar 

  7. Sonmez M, Celebi M, Berber I (2010) Eur J Med Chem 45:1935

    Article  Google Scholar 

  8. Mohamed GG, Omar MM, Ibrahim AA (2009) Eur J Med Chem 44:4801

    Article  CAS  Google Scholar 

  9. Bagihalli GB, Badami PS, Patil SA (2009) J Enzyme Inhib Med Chem 24:381

    Article  CAS  Google Scholar 

  10. Drozdzak R, Allaert B, Ledoux N, Dragutan I, Dragutan V, Verpoort F (2005) Coord Chem Rev 249:3055

    Article  CAS  Google Scholar 

  11. Gupta KC, Sutar AK (2008) Coord Chem Rev 252:1420

    Article  CAS  Google Scholar 

  12. Loginova NV, Kovalchuk TV, Zheldakova RA, Chernyavskaya AA, Osipovich NP, Glushonok GK, Polozov HI, Sorokin VL, Shadyro OI (2006) Cent Eur J Chem 4:440

    Article  CAS  Google Scholar 

  13. Yamashita N, Tanemura H, Kawanishi S (1999) Mutat Res 425:107

    CAS  Google Scholar 

  14. Sheldrick GM (1997) SHELXTL-97, program for X-ray crystal structure solution. University of Göttingen, Germany

    Google Scholar 

  15. Sheldrick GM (1997) SADABS, Siemens area detector absorption (and other) correction. University of Göttingen, Germany

    Google Scholar 

  16. Rajasekar M, Sreedaran S, Prabu R, Narayanan V, Jegadeesh R, Raaman N, Rahiman AK (2010) J Coord Chem 63:136

    Article  CAS  Google Scholar 

  17. EI-Metwally NM, Gabr IM, Shallaby AM, EI-Asmy AA (2005) J Coord Chem 58:1145

    Article  Google Scholar 

  18. Dieng M, Thiam I, Gaye M, Sall AS, Barry AH (2006) Acta Chim Slov 53:417

    CAS  Google Scholar 

  19. Arnold PJ, Davies SC, Durrant MC, Griffiths DV, Hughes DL, Sharpe PC (2003) Inorg Chim Acta 348:143

    Article  CAS  Google Scholar 

  20. Fontecha JB, Goetz S, McKee V (2002) Angew Chem Int Ed Engl 41:4553

    Article  CAS  Google Scholar 

  21. Nakao Y, Yamazaki M, Suzuki S, Mori W, Nakahara A, Matsumoto K, Ooi S (1983) Inorg Chim Acta 74:159

    Article  CAS  Google Scholar 

  22. Matsumoto K, Ooi S, Nakatsuka K, Mori W, Suzuki S, Nakahara A, Nakao Y (1985) J Chem Soc Dalton Trans 10:2095

    Article  Google Scholar 

  23. Rojo T, Larramendi JIR, Duran I, Mesa JL, Via J, Arriortua MI (1990) Polyhedron 9:2693

    Article  CAS  Google Scholar 

  24. Addison AW, Rao TN, Reedijk J, van Rijn J, Verschoor GC (1984) J Chem Soc Dalton Trans 7:1349

    Article  Google Scholar 

Download references

Acknowledgments

The author acknowledges the Pivot Construction Subject of the Applied Chemistry, and the Teaching Group of the Courses Construction on Engineering Course Chemistry for financial support.

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Authors and Affiliations

  1. College of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu, 241000, People’s Republic of China

    Zhi-Xi Hang

  2. College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, People’s Republic of China

    Bo Dong

  3. Department of Biological and Environmental Engineering, Hefei University, Hefei, 230022, People’s Republic of China

    Xing-Wen Wang

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  1. Zhi-Xi Hang
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  2. Bo Dong
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Correspondence to Zhi-Xi Hang.

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Hang, ZX., Dong, B. & Wang, XW. Synthesis and Crystal Structures of Copper(II) Complexes Derived from 5-Methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate and (2-Morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine. J Chem Crystallogr 41, 1002–1006 (2011). https://doi.org/10.1007/s10870-011-0033-7

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