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Preparation and Crystal Structural Study of a Novel Coordinated Polymer [HgI2(4-bped)2] (bped = bis(4-pyridyl)ethylene diamine)

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Abstract

A novel coordinated polymer [HgI2(4-bped)2] was synthesized through the reaction of bis(4-pyridyl)ethylene diamine and HgI2 in mixed MeOH–THF (5:2). The crystal structural analysis indicated that the complex crystallized in a monoclinic space group P21/c, a = 10.8392(12), b = 19.841(2), c = 8.8279(10), β = 95.452(2), V = 1889.9(4) Å3, Z = 4. The complex possessed a novel three-dimensional supramolecular framework formed by hydrogen bonds among repeating [HgI2(4-bped)]2 dimeric units.

Graphical Abstract

A novel coordinated polymer [HgI2(4-bped)2] was synthesized through the reaction of bis(4-pyridyl)ethylene diamine and HgI2 in mixed MeOH–THF (5:2). The crystal structural analysis indicated that the complex crystallized in a monoclinic space group P21/c, and possessed a novel three-dimensional supramolecular framework formed by hydrogen bonds among repeating [HgI2(4-bped)]2 dimeric units.

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Acknowledgment

We gratefully acknowledge the financial support of The National Science Foundation of China (20671083).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, 453000, People’s Republic of China

    Yu Liang

  2. Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, Henan, People’s Republic of China

    Fukai Zhao, Qingli Wang & Yunyin Niu

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  1. Yu Liang
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  2. Fukai Zhao
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  3. Qingli Wang
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  4. Yunyin Niu
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Correspondence to Yunyin Niu.

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Liang, Y., Zhao, F., Wang, Q. et al. Preparation and Crystal Structural Study of a Novel Coordinated Polymer [HgI2(4-bped)2] (bped = bis(4-pyridyl)ethylene diamine). J Chem Crystallogr 41, 763–766 (2011). https://doi.org/10.1007/s10870-010-9970-9

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  • DOI: https://doi.org/10.1007/s10870-010-9970-9

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