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Synthesis, Characterization and Crystal Structure of a New One-Dimensional Heterobimetallic Coordination Polymer Based on [(Tp)Fe(CN)3]−

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Abstract

By using a pre-designed anionic precursor [TpFeIII(CN)3]− (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)2Fe III2 (CN)6Zn·2H2O] n (I) has been prepared and characterized by X-ray single crystal diffraction, Mössbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) Å, b = 18.3003(10) Å, c = 12.9855(7) Å and consists of rhombic chains, in which the [TpFeIII(CN)3]− unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.

Graphical Abstract

[(Tp)2Fe III2 (CN)6Zn·2H2O] n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFeIII(CN)3]− unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.

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Acknowledgments

This work was supported by Natural Science Foundations of China (Grant 20901042), Jiangsu Province (Grant BK2010527) and in part by ‘National Basic Research Program of China’ (2009CB930601). We thank Prof. H.-C. Zhou at Department of Chemistry and Biochemistry at Miami University for collecting the crystal data and Prof. H.-B. Huang at Department of Physics at Nanjing University for performing the Mössbauer experiments.

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  1. Key Laboratory for Organic Electronics and Information Displays (KLOEID) and Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, 9 Wenyuan Road, Nanjing, 210046, China

    Shi Wang, Xuehua Ding, Wenrui He & Wei Huang

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  1. Shi Wang
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  2. Xuehua Ding
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  3. Wenrui He
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  4. Wei Huang
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Correspondence to Shi Wang.

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Wang, S., Ding, X., He, W. et al. Synthesis, Characterization and Crystal Structure of a New One-Dimensional Heterobimetallic Coordination Polymer Based on [(Tp)Fe(CN)3]− . J Chem Crystallogr 41, 737–741 (2011). https://doi.org/10.1007/s10870-010-9965-6

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