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Synthesis and Crystal Structure of a 3D Er(III) Coordination Polymer Based on Tripodal Flexible Ligand

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Abstract

Solvothermal reaction of Er(NO3)3·6H2O and tri(2-carboxyethyl)isocyanurate (H3tci) in DMF/H2O (DMF = dimethylformamide) medium leads to the generation of one new 3D coordination polymer, [Er(tci)(H2O)] DMF·2H2O (1), which was characterized by the elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 crystallizes in triclinic space group P-1, features an interesting 3D coordination framework constructed from the flexible tridentate ligand H3tci. Unit cell parameters for 1: a = 7.853(2) Å, b = 12.186(3) Å, c = 13.222(2) Å, α = 112.156(14)°, β = 105.457(15)°, γ = 91.541(18)° and Z = 2.

Graphical Abstract

Solvothermal reaction of Er(NO3)3·6H2O and tri(2-carboxyethyl)isocyanurate in DMF/H2O (DMF = dimethylformamide) medium leads to the generation of a 3D coordination polymer, which was characterized by the elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction analysis reveals that this compound crystallizes in triclinic space group P−1, features an interesting 3D coordination framework constructed by tripodal flexible ligand tri(2-carboxyethyl)isocyanurate.

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Acknowledgments

This work was granted financial support from National Natural Science Fundation of China (Grant20871063).

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, People’s Republic of China

    Guo-Xin Zhang, Wei Zhang & Zheng-Bo Han

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  1. Guo-Xin Zhang
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  2. Wei Zhang
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  3. Zheng-Bo Han
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Correspondence to Zheng-Bo Han.

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Zhang, GX., Zhang, W. & Han, ZB. Synthesis and Crystal Structure of a 3D Er(III) Coordination Polymer Based on Tripodal Flexible Ligand. J Chem Crystallogr 41, 727–731 (2011). https://doi.org/10.1007/s10870-010-9962-9

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  • DOI: https://doi.org/10.1007/s10870-010-9962-9

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