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Synthesis and Structure of Bis(3-dimethylammonium-1-propyne)pentachlorobismuthate(III) (C5H10N)2BiCl5

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Abstract

The synthesis and crystal structure are given for the bis(3-dimethylammonium-1-propyne)pentachlorobismuthate(III) salt. An X-ray investigation has shown that the title compound crystallizes at 298 K in a centrosymmetric monoclinic system, space group C2/c with the following lattice parameters a = 12.6215(4) Å, b = 18.9228(5) Å, c = 8.3134(2) Å, β = 104.100(2)°, V = 1925.70(9) Å3. The structure was solved from 7,716 independent reflections with R 1 = 0.0457 and wR 2 = 0.0906, and refined with 85 parameters. The structure consists of disordered 3-dimethylammonium-1-propyne, C5H9NH+ cations and polynuclear anions in which slightly distorted (BiCl5)2− anions, sharing an apex are interconnected in chains. These chains are themselves interconnected by means of N–H···Cl originating from the C5H9NH+ entities, forming a three-dimensional network.

Graphical Abstract

Description of the crystal structure of bis (3- dimethylammonium-1-propyne) pentachlorobismuthate (III)

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References

  1. Lazarini F (1980) Acta Crystallogr B36:2748

    CAS  Google Scholar 

  2. Blazic B, Lazarini F (1985) Acta Crystallogr C41:1619

    CAS  Google Scholar 

  3. Chaabouni S, Kamoun S, Jaud J (1998) J Chem Crystallogr 28:209

    Article  CAS  Google Scholar 

  4. Zouari F, Ben Salah A (2005) Phase Transition 78:317

    Article  CAS  Google Scholar 

  5. Wojtas′ M, Bator G, Jakubas R, Zaleski J, Kosturek B, Barand J (2003) J Solid State Chem 173:425

    Article  Google Scholar 

  6. Lefebvre J, Carpentier P, Jakubas R (1991) Acta Crystallogr B47:228

    CAS  Google Scholar 

  7. Okuda T, Tanaka N, Ichiba S, Yamada K (1986) Z Naturforsch A41:319

    Google Scholar 

  8. Piślewski N, Tritt-Goc J, Jakubas R (1996) Phys Status Solidi (b) 193:319

    Google Scholar 

  9. Ciapala P, Jakubas R, Bator G, Zaleski J, Pietraszko A, Drozd M, Baran J (1997) J Phys Condens Matter 9(3):627

    Article  CAS  Google Scholar 

  10. Farrugia LJ (1999) J Appl Crystallogr 32837:838

    Google Scholar 

  11. Brandenburg K, Berndt M (2001) Diamond Version 2.1. Crystal Impact, Bonn

    Google Scholar 

  12. International Tables for X-ray Crystallography (1992) Vol. c, Kluwer, Dordrecht

  13. Sheldrick GM (1997) SHELXS97, program for crystal structure determination. University of Göttingen, Germany

    Google Scholar 

  14. Sheldrick GM (1997) SHELXL97, program for the refinement of crystal structures. University of Göttingen, Germany

    Google Scholar 

  15. Pauling L (1960) The nature of chemical bond. Cornel University Press, Itaca, p 260

    Google Scholar 

  16. Shanon RD (1976) Acta Crystallogr A32:751

    Google Scholar 

  17. Brown ID, Altermatt D (1987) Acta Crystallogr B41:24

    Google Scholar 

  18. Brown ID, Wu KK (1976) Acta Crystallogr B32:1957

    CAS  Google Scholar 

  19. Wolfgang I, Helmar G, Khati H (2008) Acta Crystallogr E64:i46

    Google Scholar 

  20. Lakshmi S, Subramanian K (1995) Acta Crystallogr C51:2325

    CAS  Google Scholar 

  21. Lakshmi S, Subramanian K (1995) Acta Crystallogr C51:2327

    CAS  Google Scholar 

  22. Masmoudi W, Kamoun S, Ayedi HF, Driss A (2010) X-ray Struct Anal Online 26:7

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The authors thank Dr Hamdi Basma from the Faculté des Sciences de Sfax, Tunisia, for the X-ray data collection.

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Authors and Affiliations

  1. Unité de Recherche de Chimie Industrielle et Matériaux, ENIS, BP 1173, Sfax, Tunisia

    W. Masmoudi, S. Kamoun & H. F. Ayedi

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  1. W. Masmoudi
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  2. S. Kamoun
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  3. H. F. Ayedi
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Correspondence to W. Masmoudi.

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Masmoudi, W., Kamoun, S. & Ayedi, H.F. Synthesis and Structure of Bis(3-dimethylammonium-1-propyne)pentachlorobismuthate(III) (C5H10N)2BiCl5 . J Chem Crystallogr 41, 693–696 (2011). https://doi.org/10.1007/s10870-010-9955-8

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  • DOI: https://doi.org/10.1007/s10870-010-9955-8

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