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The Hydrogen-Bonded Coordination Polymer Tetracesium Bis(5-nitroisophthalate) Heptahydrate

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Abstract

The coordination polymer complex tetracesium bis(5-nitroisophthalate) heptahydrate [Cs4(C8H3NO6)2 (H2O)7] n has been synthesized and characterized using single-crystal X-ray diffraction. Crystals are monoclinic, space group P21/c, with Z = 4 in a cell with dimensions a = 12.3213(3), b = 6.7557(2), c = 36.2020(9) Å, β = 90.548(2)o. The complex is based on a repeating unit comprising four independent and different Cs coordination centres, two 6-coordinate, and two 8-coordinate [Cs–O, range 2.959(5)–3.386(5) Å], and seven water molecules, two of which are monodentate and the other five bridging, while all other oxygen atoms in the structure, including those of the nitro groups form inter-Cs bridges. Extensive water O–H···O hydrogen-bonding interactions give a three-dimensional framework. This structure represents the first of an alkali metal compound of 5-nitroisophthalic acid that has been reported.

Graphical Abstract

The coordination polymeric cesium complex with 5-nitroisophthalic acid (H2NIPA),[Cs4(NIPA)2 (H2O)7]n (1), has four separate and different coordination centres (two CsO6, two CsO8) linked through carboxyl, nitro and water oxygen bridges, giving a three-dimensional framework structure stabilized by hydrogen-bonding interactions.

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Acknowledgments

The authors acknowledge financial support from the Australian Research Council and the Faculty of Science and Technology, Queensland University of Technology.

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Authors and Affiliations

  1. Faculty of Science and Technology, Queensland University of Technology, G.P.O. Box 2434, Brisbane, QLD, 4001, Australia

    Graham Smith

  2. Faculty of Science and Technology, Queensland University of Technology, G.P.O. Box 2434, Brisbane, Queensland, 4001, Australia

    Urs D. Wermuth

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  1. Graham Smith
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  2. Urs D. Wermuth
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Correspondence to Graham Smith.

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Smith, G., Wermuth, U.D. The Hydrogen-Bonded Coordination Polymer Tetracesium Bis(5-nitroisophthalate) Heptahydrate. J Chem Crystallogr 41, 688–692 (2011). https://doi.org/10.1007/s10870-010-9953-x

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  • DOI: https://doi.org/10.1007/s10870-010-9953-x

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