Abstract
Two new complexes, namely [Cd(PDA)0.5(2,2′-bpy)Cl](H2PDA) (1) and [Ni(PDA)(phen)(H2O)]2 (2) (H2PDA = 1,4-phenylenediacetic acid, 2,2′-bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline), have been synthesized and characterized by elemental analysis, IR spectra and X-ray crystal diffraction. Single-crystal X-ray diffraction analysis shows that complex 1 crystallizes in the triclinic space group P-1 with unit cell dimensions a = 8.760 (4) Å, b = 11.190 (5) Å, c = 13.917 (7) Å, α = 110.383 (5)°, β = 101.736 (5)°, γ = 100.612 (5)°, V = 1202.8 (10) Å3, Z = 2, R 1 = 0.0314 and wR 2 = 0.0898. Complex 2 crystallizes in the monoclinic space group P2(1)/n with unit cell dimensions a = 9.911 (3) Å, b = 17.924 (6) Å, c = 10.638 (4) Å, β = 94.998 (5)°, V = 1882.7 (11) Å3, Z = 2, R 1 = 0.0397 and wR 2 = 0.1150. In complex 1, Cd(II) ions are alternately bridged by PDA ligands and chloride ions into 1D chains and the PDA ligands display trans-configuration. Complex 2 is a dimer and two Ni(II) ions are linked by two PDA ligands with cis-configuration, resulting in a cyclic structure. In spite of these differences, both in complexes 1 and 2 there are π–π stacking interactions and hydrogen bonding to make them 3D supramolecular frameworks.
Graphical Abstract
Two new complexes [Cd(PDA)0.5(2,2′-bpy)Cl](H2PDA) and [Ni(PDA)(phen)(H2O)]2 (H2PDA = 1,4-phenylenediacetic acid, phen = 1,10-phenanthroline, 2,2′-bpy = 2,2′-bipyridine) were obtained and their structures were determined by single crystal X-ray diffraction. In complex [Cd(PDA)0.5(2,2′-bpy)Cl](H2PDA), Cd(II) ions are alternately bridged by PDA ligands and chloride ions into 1D chains and the PDA ligands display trans-configuration. The complex [Ni(PDA)(phen)(H2O)]2 is the first nickel(II) complex constructed by H2PDA. And two Ni(II) ions in one unit are linked by two PDA ligands with cis-configuration, resulting in a cyclic structure.
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References
Batten SR, Robson R (1998) Angew Chem Int Ed 37:1460–1494
Leininger S, Olenyuk B, Stang PJ (2000) Chem Rev 100:853–908
Swiegers GF, Malefetse TJ (2000) Chem Rev 100:3483–3538
Moulton B, Zaworotko MJ (2001) Chem Rev 101:1629–1658
Holliday BJ, Mirkin CA (2001) Angew Chem Int Ed 40:2022–2043
Eddaoudi M, Moler DB, Li H, Chen B, Reineke TM, O’Keeffe M, Yaghi OM (2001) Acc Chem Res 34:319–330
Caulder DL, Raymond KN (1999) Acc Chem Res 32:975–982
Song LF, Jiang CH, Jiao CL, Zhang J, Sun LX, Xu F, You WS, Wang ZG, Zhao JJ (2010) Cryst Growth Des 10:5020–5023
Sun D, Wang DF, Zhang N, Huang RB, Zheng LS (2010) Cryst Growth Des 10:5031–5033
An HY, Han ZB, Xu TQ (2010) Inorg Chem 49:11403–11414
Rodríguez-Martín Y, Hernández-Molina M, Delgado FS, Pasán J, Ruiz-Pérez C, Sanchiz J, Lloret F, Julve M (2002) CrystEngComm 4:522–535
Murray LJ, Dincă M, Long JR (2009) Chem Soc Rev 38:1294–1314
Kurmoo M (2009) Chem Soc Rev 38:1353–1379
Jenkins DM, Bernhard S (2010) Inorg Chem 49:11297–11308
Li JR, Kuppler RJ, Zhou HC (2009) Chem Soc Rev 38:1477–1504
Ye BH, Tong ML, Chen XM (2005) Coord Chem Rev 249:545–565
Zhou J, Sun CY, Jin LP (2007) J Mol Struct 832:55–62
Singh WM, Baruah JB (2009) Inorg Chem Acta 362:4268–4271
Blessing RH (1995) Acta Crystallogr A 51:33–38
Sheldrick GM (1997) SHELXS97 and SHELXL97. University of Göttingen, Gottingen
Altomare A et al (1999) J Appl Crystallogr 32:115–119
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The authors thank the National Natural Science Foundation of China (20761002), PR China and the Natural Science Foundation of Guangxi (0832080), PR China.
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Wu, QL., Luo, ZR., Zhuang, JC. et al. Syntheses and Crystal Structures of Two New Cadmium(II) and Nickel(II) Complexes with 1,4-Phenylenediacetate and 2,2′-Bipyridyl-Like Ligands. J Chem Crystallogr 41, 664–669 (2011). https://doi.org/10.1007/s10870-010-9948-7
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DOI: https://doi.org/10.1007/s10870-010-9948-7