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Synthesis, Structure and Electrochemical Property of a New Copper(II) Complex Based on Benzene-1,2,4,5-tetracarboxylate and 2,5-Bis(3-pyridyl)-1,3,4-oxadiazole Ligands

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Abstract

A new three-dimensional (3-D) supramolecular complex, [Cu2(btec)(bpo)2(H2O)2]·8H2O (1), has been synthesized by hydrothermal reaction with the mixed ligands benzene-1,2,4,5-tetracarboxylate (btec) and bent dipyridyl based ligand 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (bpo), and structurally characterized by elemental analysis, IR, TG, powder-XRD and single-crystal X-ray diffraction analysis. The results reveal that each Cu(II) ion is bridged by two different ligands (btec and bpo) to form a 2-D polymer layer in complex 1. The adjacent layers are further linked by 1-D H-bonded water chains simultaneously containing (H2O)6 rings and (H2O)8 rings to form a 3-D supramolecular framework. Moreover, the electrochemical behavior of complex 1 bulk-modified carbon paste electrode (1-CPE) has been reported.

Graphical Abstract

A new three-dimensional supramolecular complex, [Cu2(btec)(bpo)2(H2O)2]·8H2O (1), has been synthesized by hydrothermal reaction with the mixed ligands benzene-1,2,4,5-tetracarboxylate (btec) and bent dipyridyl based ligand 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (bpo).

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Acknowledgments

This work was supported by the NCET-09-0853, the National Natural Science Foundation of China (No. 20871022), and the Education Office Foundation of Liaoning Province (No. 2009R03).

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou, 121000, People’s Republic of China

    Hong-Yan Lin, Bao Mu, Xiu-Li Wang, Jin Li & Guo-Cheng Liu

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  1. Hong-Yan Lin
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  2. Bao Mu
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  3. Xiu-Li Wang
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  4. Jin Li
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  5. Guo-Cheng Liu
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Correspondence to Xiu-Li Wang.

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Lin, HY., Mu, B., Wang, XL. et al. Synthesis, Structure and Electrochemical Property of a New Copper(II) Complex Based on Benzene-1,2,4,5-tetracarboxylate and 2,5-Bis(3-pyridyl)-1,3,4-oxadiazole Ligands. J Chem Crystallogr 41, 635–640 (2011). https://doi.org/10.1007/s10870-010-9944-y

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