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The Structure and Fluorescence Property of a 3D Supramolecular Network [Cd2(2-mBIM)2Cl2(C4H4O4)(H2O)2(H2O)] n

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Abstract

A cadmium(II) coordination polymer [Cd2(2-mBIM)2Cl2(C4H4O4)(H2O)2(H2O)] n (1) (wherein 2-mBIM = bis(2-methylimidazo-1-yl) methane, C4H4O4 = succinate anion) has been synthesized and characterized by X-ray diffraction. Complex 1 crystallizes in the monoclinic space group C2/c with a = 23.5265(15) Å, b = 7.3558(5) Å, c = 17.4771(11) Å, β = 90.3560(10)°, V = 3024.5(3) Å3, Z = 4. Each Cd(II) atom is octahedrally coordinated and connected with two adjacent Cd(II) atoms by two individual 2-mBIM ligands in a trans-configuration to form one-dimensional (1D) helical structure. Such 1D helical chain structures were connected to each other via the succinate anion ligands and result in the formation of a two-dimensional (2D) framework. Meanwhile, an overall three-dimensional (3D) supramolecular network was formed via the weak hydrogen bond interactions between metal-coordination and free water molecules.

Graphical Abstract

A cadmium(II) coordination polymer has been synthesized and its single crystal structure shows that an overall 3D supramolecular network was formed via the weak hydrogen bond between adjacent 2D layer framework containing 1D helical chain structure.

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Acknowledgments

This work was supported by the Natural Science Foundation of Hubei Province (2009CDB349, 2006ABB038), the Distinguished Young Scholars’ Programs, HBDE (Q200722003, Z201022001, CXY2009B028) and the Science and Technology Foundation for Creative Research Group of HBNU (2009).

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Authors and Affiliations

  1. Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, College of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi, 435002, Hubei, People’s Republic of China

    Min Pi, Zhe Zhang & Chuan-Ming Jin

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  1. Min Pi
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  2. Zhe Zhang
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  3. Chuan-Ming Jin
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Correspondence to Chuan-Ming Jin.

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Pi, M., Zhang, Z. & Jin, CM. The Structure and Fluorescence Property of a 3D Supramolecular Network [Cd2(2-mBIM)2Cl2(C4H4O4)(H2O)2(H2O)] n . J Chem Crystallogr 41, 630–634 (2011). https://doi.org/10.1007/s10870-010-9942-0

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