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Crystal Structure of the Second Polymorph of Octaethylporphyrin Iron(III) with Monoanion 1,4-Phenyldicyanamide, [Fe(OEP)(DicydH)]

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Abstract

Molecular structure of the second polymorph of [Fe(OEP)(DicydH)], where OEP is the dianion of octaethylporphyrin and DicydH = monoanion of 1,4-phenyldicyanamide, was determined by single-crystal X-ray diffraction. Fe(III) atom is five-coordinate to four N atoms of the porphyrin ring and to one nitrogen atom of DicydH. The compound is characterized by an average Fe–Np bond length of 2.057 Å. The Fe–Nax bond distance is 1.969(6) Å. Crystal data: crystal system, orthorhombic, a = 15.048(2), b = 17.515(3), c = 29.440(4) Å, space group, Pcab, V = 7759(2) Å3, Z = 8.

Index Abstract

Molecular structure of the second polymorph of [Fe(OEP)(DicydH)], where OEP is the dianion of octaethylporphyrin and DicydH is monoanion of 1,4-phenyldicyanamide, has been characterized by single-crystal X-ray diffraction.

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Acknowledgment

We thank University of Sistan and Baluchestan (USB) for financial support (GN: 85g02).

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Authors and Affiliations

  1. Department of Chemistry, University of Sistan and Baluchestan, 98155-147, Zahedan, Iran

    Mozhgan Khorasani-Motlagh, Meissam Noroozifar & Jilla Saffari

  2. Department of Chemistry, Shahid Beheshti University, Tehran, Iran

    Hamid Reza Khavasi

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  1. Mozhgan Khorasani-Motlagh
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  2. Meissam Noroozifar
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  3. Jilla Saffari
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  4. Hamid Reza Khavasi
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Correspondence to Mozhgan Khorasani-Motlagh.

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Khorasani-Motlagh, M., Noroozifar, M., Saffari, J. et al. Crystal Structure of the Second Polymorph of Octaethylporphyrin Iron(III) with Monoanion 1,4-Phenyldicyanamide, [Fe(OEP)(DicydH)]. J Chem Crystallogr 41, 625–629 (2011). https://doi.org/10.1007/s10870-010-9941-1

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