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Synthesis and Structure of a CdI2 Coordination Polymer with 1,1′-(1,4-Butanediyl)bis-1H-benzotriazole(bbbt)

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Abstract

In this article, solution reaction of cadmium iodide with organic multifunctional ligand 1,1′-(1,4-butanediyl)bis-1H-benzotriazole(bbbt) generated a 1D polymer [CdI2 (bbbt) (CH3OH)]n 1, and the crystal structure has been determined (C17 H20 Cd I2 N6 O), Mr = 690.59 a = 10.032(2), b = 13.503(3), c = 16.706(3) Å, space group C2/c, Z = 4, and V = 2223.1(8) Å3. In 1 the tetrahedral coordination of Cd(II) and the conformation of bbbt ligand make it a wave-shaped structure.

Graphical Abstract

Solution reaction of cadmium iodide with organic multifunctional ligand 1,1′-(1,4-butanediyl)bis-1H-benzotriazole(bbbt) generated a 1D polymer [CdI2 (bbbt) (CH3OH)] n , in which the tetrahedral coordination of Cd(II) and the conformation of bbbt ligand make it a wave-shaped structure.

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Acknowledgements

This research was funded by the National Natural Science Foundation (Grant No. 20671083) and the Science Foundation for Distinguished Young Scholars of Henan Province (Grant No. 0612002800).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, 453000, People’s Republic of China

    Yu Liang

  2. Chemical and Biological Department, Henan Jiaozuo Teacher’s College, Jiaozuo, 454000, People’s Republic of China

    Mei Liu

  3. Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, People’s Republic of China

    Ning Zhang, Qingli Wang, Yunyin Niu, Xiucun Liu & Hongwei Hou

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  1. Yu Liang
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  2. Mei Liu
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  3. Ning Zhang
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  6. Xiucun Liu
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Correspondence to Yunyin Niu.

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Liang, Y., Liu, M., Zhang, N. et al. Synthesis and Structure of a CdI2 Coordination Polymer with 1,1′-(1,4-Butanediyl)bis-1H-benzotriazole(bbbt). J Chem Crystallogr 41, 617–620 (2011). https://doi.org/10.1007/s10870-010-9934-0

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  • DOI: https://doi.org/10.1007/s10870-010-9934-0

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