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Crystal Structure of Cis-Dichloro-Bis-{[2-(Diphenylphosphino-κ-P) Methyl]Diphenylphosphine Oxide}Palladium(II) Ethanol Solvate

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Abstract

The title compound cis-Cl2Pd [P(Ph)2PCH2P(O)Ph2]2 crystallizes in the monoclinic space group, P21/c with crystal cell parameters a = 13.076(5) Å, b = 12.931(5) Å, c = 27.465(9) Å, β = 92.661(6)o, V = 4639(3) Å3, Z = 4. The bulk of the phenyl groups prohibits the molecule from assuming a conformation that would permit both P=O groups to coordinate another metal ion.

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Acknowledgments

The support of the National Science Foundation (REU Grants CHE-0754521 and CHE-0315345) is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, MSC 4501, James Madison University, Harrisonburg, VA, 22807, USA

    Ashley R. Head, Donna S. Amenta & John W. Gilje

  2. Department of Chemistry and Biochemistry, University of Delaware, Newark, DE, 19716, USA

    Glenn P. A. Yap

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  1. Ashley R. Head
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  2. Donna S. Amenta
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  3. John W. Gilje
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  4. Glenn P. A. Yap
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Correspondence to Glenn P. A. Yap.

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Head, A.R., Amenta, D.S., Gilje, J.W. et al. Crystal Structure of Cis-Dichloro-Bis-{[2-(Diphenylphosphino-κ-P) Methyl]Diphenylphosphine Oxide}Palladium(II) Ethanol Solvate. J Chem Crystallogr 41, 247–250 (2011). https://doi.org/10.1007/s10870-010-9922-4

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  • DOI: https://doi.org/10.1007/s10870-010-9922-4

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