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2D d10 Metal Assembly Frameworks: Construction of Metal–organic Architecture with Metal Thiocyanate and Dipyridyl Spacer

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Abstract

A new coordination polymer based on Group IB metal thiocyanates, [Ag I2 (NCS)2(dpds)2]n (1) (dpds = 2,2′-dipyridyldisulfide), has been synthesized by the pre-assembly method and characterized by X-ray crystallography. In 1, the AgI center adopts tetrahedral coordination geometry and the 2-D undulated layers of (4, 4) topology network is formed by dpds ligand with zigzag NCS−Ag chains.

Graphical Abstract

A new coordination polymer based on Group IB metal thiocyanates, [Ag I2 (NCS)2(dpds)2]n (1) (dpds = 2,2′-dipyridyldisulfide), has been synthesized by the pre-assembly method and characterized by X-ray crystallography. In 1, the AgI center adopts tetrahedral coordination geometry and the 2-D undulated layers of (4, 4) topology network is formed by dpds ligand with zigzag NCS−Ag chains.

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References

  1. Fujita M, Kwon YJ, Washizu S, Ogura K (1994) J Am Chem Soc 116:1151

    Article  CAS  Google Scholar 

  2. Withersby MA, Blake AJ, Champness NR, Hubberstey P, Li WS, Schröder M (1997) Angew Chem Int Ed Engl 36:2327

    Article  CAS  Google Scholar 

  3. Jay JI, Padgett CW, Walsh RDB, Hanks TW, Pennington WT (2001) Cryst Growth Design 1:501

    Article  CAS  Google Scholar 

  4. Lehn JM, Chemistry Supramolecular (1995) Concepts and perspectives. Vch, Weinheim

    Google Scholar 

  5. Niu YY, Zhang N, Hou HW, Zhu Y, Tang MS, Ng SW (2007) J Mol Stru 827(1–3):195–200

    Article  CAS  Google Scholar 

  6. Delgado S, Barrilero A, Molina-Ontoria A, Medina ME, Pastor CJ, Jimenez-Aparicio R, Priego JL (2006) Eur J Inorg Chem 14:2746

    Article  Google Scholar 

  7. Kubo S, Nishioka T, Ishikawa K, Kinoshita I, Isobe K (1998) Chem Lett 10:1067

    Article  Google Scholar 

  8. Jung OS, Park SH, Kim DC, Kim KM (1998) Inorg Chem 37:610

    Article  CAS  Google Scholar 

  9. Niu YY, Zheng HG, Hou HW, Xin XQ (2004) Coord Chem Rev 248:169

    Article  CAS  Google Scholar 

  10. Sheldrick GM (1993) SHELXL93. University of Göttingen, Germany

    Google Scholar 

  11. Niu YY, Song YL, Hou HW, Zhu Y (2005) Inorg Chem 44:2553

    Article  CAS  Google Scholar 

  12. Niu YY, Song YL, Zhang N, Hou HW, Che DJ, Fan YT, Zhu Y, Duan CY (2006) Eur J Inorg Chem 11:2259

    Article  Google Scholar 

Download references

Acknowledgments

This research was funded by the NSFC (Grant no. 20671083), the SPDYS of Henan Province (nos. 0612002800, 64100002800), and the UITP of ZZU (Grant no. 2007CXSY044).

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Authors and Affiliations

  1. Henan Chemical Industry Research Institute, Zhengzhou, 450052, Henan, China

    Zhong-Ming Gu

  2. Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, Henan, People’s Republic of China

    Qing-Li Wang, Yun-Yin Niu, Xiao-Ling Guo, Hong-Wei Hou, Yao-Ting Fan & Dong Sun

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  1. Zhong-Ming Gu
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  2. Qing-Li Wang
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  3. Yun-Yin Niu
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Correspondence to Yun-Yin Niu or Hong-Wei Hou.

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Gu, ZM., Wang, QL., Niu, YY. et al. 2D d10 Metal Assembly Frameworks: Construction of Metal–organic Architecture with Metal Thiocyanate and Dipyridyl Spacer. J Chem Crystallogr 41, 533–536 (2011). https://doi.org/10.1007/s10870-010-9915-3

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