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Base-Stabilized Monomeric Stibinoalane dmap–Al(Et2)Sb(tBu)2

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Abstract

The six-membered heterocycle [Me2AlSb(t-Bu)2]3 was reacted with the strong Lewis-base 4-dimethylaminopyridine (dmap), yielding the first completely alkyl-substituted monomeric complex dmap–Al(Me2)Sb(t-Bu)2 1. 1 was characterized by NMR spectroscopy and single crystal X-ray diffraction. 1 is monoclinic, space group P2 1 /n with a = 9.9004(2) Å, b = 16.8166(3) Å, c = 13.8400(3) Å, β = 100.746(1)° and Z = 4.

Index Abstract

The synthesis and single crystal X-ray analysis of the first completely alkyl-substituted monomeric complex dmap–Al(Me2)Sb(t-Bu)2, which was obtained from the ring cleavage reaction of [Me2AlSb(t-Bu)2]3 with dmap, is described.

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Acknowledgments

Stephan Schulz gratefully acknowledges financial support by the German Research Foundation.

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Authors and Affiliations

  1. Chemistry Department, University of Duisburg-Essen, Universitätsstr. 5-7, 45117, Essen, Germany

    Stephan Schulz

  2. Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, PO Box 55, A.I. Virtasen Aukio 1, FIN-00014, Helsinki, Finland

    Martin Nieger

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  1. Stephan Schulz
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  2. Martin Nieger
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Correspondence to Stephan Schulz.

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Schulz, S., Nieger, M. Base-Stabilized Monomeric Stibinoalane dmap–Al(Et2)Sb(tBu)2 . J Chem Crystallogr 41, 349–352 (2011). https://doi.org/10.1007/s10870-010-9886-4

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  • DOI: https://doi.org/10.1007/s10870-010-9886-4

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