Skip to main content
SpringerLink
Log in

Hydrogen-bonded Three-dimensional Supramolecular Network Constructed by Dinuclear Ni(II) Macrocyclic Complex and 1,2,4,5-Benzenetetracarboxylate

  • ORIGINAL PAPER
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new coordination polymer [Ni2(L)(H2btec)]n, (1) was obtained from the reaction of NiSO4·6H2O, macrocyclic ligand 3,6,9,17,20,23-hexaaza-29,30-dihydroxy-13,27-di-tert-butyl-tricyclo[23,3,1,111,15]triaconta-1(28),11,13,15(30),25,26-hexaene (H2L), and 1,2,4,5-benzenetetracarboxylic acid (H4btec) in methanol. Its structure was determined by X-ray diffraction analysis. The crystal is monoclinic C2/c space group with cell parameters a = 20.4923(3) Å, b = 14.2389(3) Å, c = 14.5130(2) Å, β = 97.441(2)°, V = 4199.05(12) Å3, and Z = 8. The X-ray analysis shows that each Ni (II) cation is six-coordinated by an O3N3 donor set. The macrocyclic complex [Ni2L] 2+ are bridged by H2btec2− anions to form 1D chains, which are further joined via N–H···O hydrogen bonds to yield a 3D supramolecular structure. Thermogravimetric analysis (TGA) for the complex is discussed.

Graphical Abstract

The macrocyclic complexes [Ni2L] 2+ are bridged by H2btec2− anions to form 1D chains, which are further joined via N—H···O hydrogen bonds to yield a 3D supramolecular structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Vigato PA, Tamburini S, Fenton DE (1990) Coord Chem Rev 106:25

    Article  CAS  Google Scholar 

  2. Koike T, Inoue M, Kimura E, Shiro M (1996) J Am Chem Soc 118:3091

    Article  CAS  Google Scholar 

  3. Kimura E, Kodama Y, Koike T, Shiro M (1995) J Am Chem Soc 117:8304

    Article  CAS  Google Scholar 

  4. Vance DH, Czarnik AW (1993) J Am Chem Soc 115:12165

    Article  CAS  Google Scholar 

  5. Chung Y, Akkaya EU, Venkatachalam TK, Czarnik AW (1990) Tetrahedron Lett 31:5413

    Article  CAS  Google Scholar 

  6. Hay RW, Govan N (1997) Polyhedron 16:4233

    Article  CAS  Google Scholar 

  7. Ragunathan KG, Schneider H-J (1996) Angew Chem Int Ed Engl 35:1219

    Article  CAS  Google Scholar 

  8. Manif R, Martell AE (1989) J. Chem. Soc., Chem. Commun. 1521

  9. Kawabata S, Soma T, Ichikawa K (1997) Chem. Lett. 1199

  10. Bazzicalupi C, Bencini A, Bianchi A, Cecchi M, Escuder B, Fusi V, Garcia-Espan˜a E, Giorgi C, Luis SV, Maccagni G, Marcelino V, Paoletti P, Valtancoli B (1999) J Am Chem Soc 121:6807

    Article  CAS  Google Scholar 

  11. Nation DA, Martell AE, Carroll RI, Clearfield A (1996) Inorg Chem 35:7246

    Article  CAS  Google Scholar 

  12. Nation DA, Reibenspies J, Martell AE (1996) Inorg Chem 35:4597

    Article  CAS  Google Scholar 

  13. Li K, Fernandez-Saiz M, Rigl CT, Kumar A, Ragunathan KG, Mcconnaughie AW, Boykin DW, Schneider H-S (1997) Bioorg Med Chem 5:1157

    Article  CAS  Google Scholar 

  14. Lu Q, Carroll RI, Reibenspies JH, Martell AE, Clearfield A (1998) J Mol Struct 470:121

    Article  CAS  Google Scholar 

  15. Ross E, Motekaitis RJ, Martell AE (1999) Inorg Chim Acta 286:55

    Article  CAS  Google Scholar 

  16. Pauwels TF, Lippens W, Smet PWS, Herman GG, Goeminne AM (1999) Polyhedron 18:1029

    Article  CAS  Google Scholar 

  17. Wang M, Zhang G, Chen D, Jiang M, Liu S (2001) Macromolecules 34:7172

    Article  CAS  Google Scholar 

  18. Duan H, Chen D, Jiang M, Gan W, Li S, Wang M, Gong J (2001) J Am Chem Soc 123:12097

    Article  CAS  Google Scholar 

  19. Middelbeek HS, Noltes R (1999) J M Science 284:785

    Google Scholar 

  20. Gao J, Reibenspies JH, Martell AE (2003) Inorg Chim Acta 346:67

    Article  CAS  Google Scholar 

  21. Gao J, Martell AE, Reibenspies JH (2003) Inorg Chim Acta 346:32

    Article  CAS  Google Scholar 

  22. Gao J, Martell AE, Reibenspies JH (2002) Inorg Chim Acta 329:122

    Article  CAS  Google Scholar 

  23. Kong DY, Martell AE, Reibenspies J (2002) Inorg Chim Acta 333:7

    Article  CAS  Google Scholar 

  24. He WJ, Liu F, Duan CY, Guo ZJ, Zhou SZ, Liu YJ, Zhu LG (2001) Inorg Chem 40:7065

    Article  CAS  Google Scholar 

  25. Liu J, Ping GJ, Li QJ, Ma JF (2007) Acta Cryst E63:m3172

    CAS  Google Scholar 

  26. Verani CN, Rentschler E, Weyhermüller T, Bill E, Chaudhuri P (2000) J. Chem. Soc., Dalton Trans. 251

  27. Shangguan GQ, Martell AE, Zhang ZR, Reibenspies JH (2000) Inorg Chim Acta 299:47

    Article  CAS  Google Scholar 

  28. Bruker (1999) SADABS. Bruker AXS, Madison

    Google Scholar 

  29. Sheldrick GM (1997) SHELXS-97, a program for automatic solution of crystal structure. University of Goettingen, Germany

    Google Scholar 

  30. Sheldrick GM (1997) SHELXS-97, a program for crystal structure refinement. University of Goettingen, Germany

    Google Scholar 

  31. Farrugia J (1998) WINGX, a windows program for crystal structure analysis. University of Glasgow, UK

    Google Scholar 

Download references

Acknowledgments

We thank Program for Changjiang Scholars and Innovative Research Teams in Chinese University, the Specialized Research Fund for the Doctoral Program of Higher Education, the China Postdoctoral Science Foundation (20080431050 and 200801352), the Postdoctoral Foundation of Northeast Normal University, the Training Fund of NENU’S Scientific Innovation Project, and the Analysis and Testing Foundation of Northeast Normal University for support.

Author information

Authors and Affiliations

  1. Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Ying-Yin Jiang, Jian-Fang Ma, Ying-Ying Liu & Jin Yang

Authors
  1. Ying-Yin Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jian-Fang Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ying-Ying Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jin Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jian-Fang Ma.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jiang, YY., Ma, JF., Liu, YY. et al. Hydrogen-bonded Three-dimensional Supramolecular Network Constructed by Dinuclear Ni(II) Macrocyclic Complex and 1,2,4,5-Benzenetetracarboxylate. J Chem Crystallogr 41, 286–290 (2011). https://doi.org/10.1007/s10870-010-9874-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-010-9874-8

Keywords

Search

Navigation