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Synthesis and Crystal Structure of Tetrabutylammonium 4-(2-Bromothiophene-5-Sulfanilamide)-Benzoate

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Abstract

Tetrabutylammonium 4-(2-bromothiophene-5-sulfanilamide)-benzoate crystallizes in C2/C lattice with a = 18.3389(17), b = 16.540(16), c = 15.8280(15) Å, β = 116.959(2), V = 4279.5(7) Å3, Z = 4, and R = 0.0560. In the structure a very short centrosymmetric hydrogen bond and C=O···Br halogen bond interactions, together with N–H···O and C–H···O hydrogen bonds give a three-dimensional network.

Graphical Abstract

A extremely short O–H···O hydrogen bond is observed between the two neighboring 4-(2-bromothiophene-5-sulfanilamide)-benzoates. The H atom is fixed at the crystallographic inversion center and bridges the two benzoates to form an anion dimer. Halogen bonds also aid in forming the interest structure in crystal.

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Authors and Affiliations

  1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325027, People’s Republic of China

    Jing Xiong

  2. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, 310014, People’s Republic of China

    Yun Guo & Zhi Min Jin

  3. Zhejiang Environmental Monitoring Centre, Hangzhou, 310012, People’s Republic of China

    Zhen-Yu Li

Authors
  1. Jing Xiong
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  2. Yun Guo
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  3. Zhen-Yu Li
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  4. Zhi Min Jin
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Correspondence to Zhi Min Jin.

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Xiong, J., Guo, Y., Li, ZY. et al. Synthesis and Crystal Structure of Tetrabutylammonium 4-(2-Bromothiophene-5-Sulfanilamide)-Benzoate. J Chem Crystallogr 40, 884–887 (2010). https://doi.org/10.1007/s10870-010-9848-x

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