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X-ray Structure of mer-[Mo(CO)3(PPh3)(κ 2-dppm)]

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Abstract

Treatment of [Mo(CO)3(NCMe)3] with bis(diphenylphosphino)methane (dppm) and triphenylphosphine (PPh3) at 50 °C afforded mer-[Mo(CO)3(PPh3)(κ 2-dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P−1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) Å, β = 80.8400(10)°, Z = 2 and V = 1959.8(2) Å3.

Graphical Abstract

Synthesis and molecular structure of mer-[Mo(CO)3(PPh3)(κ 2-dppm)] are described

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Scheme 1
Fig. 1

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Acknowledgments

Financial support of this work by the University Grants Commission of Bangladesh is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Jahangirnagar University, Savar, Dhaka, 1342, Bangladesh

    Shishir Ghosh, Shariff E. Kabir, Farzana K. Camellia & Md. Kamal Hossain

  2. Department of Chemistry, Marquette University, Milwaukee, WI, 53201-1881, USA

    Daniel T. Haworth & Sergey V. Lindeman

  3. Department of Chemistry, University of Wisconsin-Milwaukee, P.O. Box 413, Milwaukee, WI, 53211-3029, USA

    Tasneem A. Siddiquee & Dennis W. Bennett

Authors
  1. Shishir Ghosh
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  2. Shariff E. Kabir
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  3. Farzana K. Camellia
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  4. Md. Kamal Hossain
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  5. Daniel T. Haworth
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  6. Sergey V. Lindeman
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  7. Tasneem A. Siddiquee
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  8. Dennis W. Bennett
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Corresponding author

Correspondence to Shariff E. Kabir.

Additional information

D. T. Haworth died on July 6, 2009, at the age of 81.

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Ghosh, S., Kabir, S.E., Camellia, F.K. et al. X-ray Structure of mer-[Mo(CO)3(PPh3)(κ 2-dppm)]. J Chem Crystallogr 40, 712–715 (2010). https://doi.org/10.1007/s10870-010-9777-8

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  • DOI: https://doi.org/10.1007/s10870-010-9777-8

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